Hydration of aromatic terminal alkynes catalyzed by sulfonated condensed polynuclear aromatic (S-COPNA) resin in water

被引：7

作者：

Tanemura, Kiyoshi ^{[1
]}

Suzuki, Tsuneo ^{[1
]}

机构：

[1] Nippon Dent Univ, Sch Life Dent Niigata, Chem Lab, Niigata 9518580, Japan

来源：

TETRAHEDRON LETTERS | 2017年 / 58卷 / 10期

关键词：

Hydration; Alkynes; Water; Ketones; Solid acids; Acid catalysts; MARKOVNIKOV HYDRATION; ACID; POLYPYRENE; COMPLEXES;

D O I：

10.1016/j.tetlet.2017.01.072

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydration of aromatic terminal alkynes in the presence of a catalytic amount of sulfonated condensed polynuclear aromatic (S-COPNA) resin in water gave the corresponding methyl ketones in good yields. On the other hand, aliphatic terminal alkynes did not react at all under the employed conditions. Chemoselective hydration of aromatic terminal alkyne in the presence of aliphatic terminal alkyne catalyzed by S-COPNA resin was carried out. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：955 / 958

页数：4

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