Molecular and Supramolecular Networks on Surfaces: From Two-Dimensional Crystal Engineering to Reactivity

被引:569
|
作者
Elemans, Johannes A. A. W. [1 ]
Lei, Shengbin [1 ]
De Feyter, Steven [1 ]
机构
[1] Katholieke Univ Leuven, INPAC, B-3001 Louvain, Belgium
关键词
crystal engineering; chirality; nanostructures; scanning tunneling microscopy; supramolecular chemistry; LIQUID-SOLID INTERFACE; SCANNING-TUNNELING-MICROSCOPY; SELF-ASSEMBLED MONOLAYERS; ASSISTED COORDINATION CHEMISTRY; SOLVENT-INDUCED POLYMORPHISM; ALKYL CHAIN INTERDIGITATION; TRIMESIC ACID; ACHIRAL MOLECULES; ULTRAHIGH-VACUUM; FLUORESCENCE SPECTROSCOPY;
D O I
10.1002/anie.200806339
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The invention of the scanning tunneling microscope has led to the visualization of molecules in real space on atomically flat conductive substrates. This has boosted research into supramolecular chemistry on surfaces. In this Review, we highlight recent developments in the design and functionality of supramolecular surface patterns, with special attention paid to those networks which are chiral or contain a high degree of porosity as well as to the reactivity, which is one of the most important recent developments in supramolecular surface chemistry. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:7298 / 7332
页数:35
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