Synthesis of block copolymers of styrene and methyl methacrylate by conventional free radical polymerization in room temperature ionic liquids

被引：158

作者：

Zhang, HW ^{[1
]}

Hong, KL ^{[1
]}

Mays, JW ^{[1
]}

机构：

[1] Univ Alabama Birmingham, Dept Chem, Birmingham, AL 35294 USA

来源：

MACROMOLECULES | 2002年 / 35卷 / 15期

关键词：

D O I：

10.1021/ma025518x

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Block copolymers of styrene and methyl methacrylate (MMA) were made by sequential addition of the monomers in the room-temperature ionic liquid [C4mim]PF6 using BPO as the initiator. The polymerization products were characterized by SEC, NMR, and DSC. As such, fractional precipitation experiments provided definite evidence of the formation of PS-b-PMMA block copolymers.

引用

页码：5738 / 5741

页数：4

共 34 条

[1] Electrochemical synthesis of polyphenylene in a new ionic liquid [J].

Arnautov, SA .

SYNTHETIC METALS, 1997, 84 (1-3) :295-296

[2]

Bamford CH, 1988, ENCY POLYM SCI ENG, P708

[3]

BIENDRON T, 2001, MACROMOL RAPID COMM, V22, P1237

[4]

Brandrup J., 1999, Polymer handbook, VII

[5] A SILANE-BASED ELECTROACTIVE FILM PREPARED IN AN IMIDAZOLIUM CHLOROALUMINATE MOLTEN-SALT [J].

CARLIN, RT ;

OSTERYOUNG, RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) :1709-1713

[6] STUDIES OF TITANIUM(IV) CHLORIDE IN A STRONGLY LEWIS ACIDIC MOLTEN-SALT - ELECTROCHEMISTRY AND TITANIUM NMR AND ELECTRONIC SPECTROSCOPY [J].

CARLIN, RT ;

OSTERYOUNG, RA ;

WILKES, JS ;

ROVANG, J .

INORGANIC CHEMISTRY, 1990, 29 (16) :3003-3009

[7] COMPLEXATION OF CP2MCL2 IN A CHLOROALUMINATE MOLTEN-SALT - RELEVANCE TO HOMOGENEOUS ZIEGLER-NATTA CATALYSIS [J].

CARLIN, RT ;

WILKES, JS .

JOURNAL OF MOLECULAR CATALYSIS, 1990, 63 (02) :125-129

[8] Copper(I) mediated living radical polymerisation in an ionic liquid [J].

Carmichael, AJ ;

Haddleton, DM ;

Bon, SAF ;

Seddon, KR .

CHEMICAL COMMUNICATIONS, 2000, (14) :1237-1238

[9]

Francuskiewicz F., 1994, POLYM FRACTIONATION

[10] BENZENE POLYMERIZATION IN 1-ETHYL-3-METHYLIMIDAZOLIUM CHLORIDE ALCL3 IONIC LIQUID [J].

GOLDENBERG, LM ;

OSTERYOUNG, RA .

SYNTHETIC METALS, 1994, 64 (01) :63-68

← 1 2 3 4 →