Extending the toolbox for gas sensor research: Operando UV/vis diffuse reflectance spectroscopy on SnO2-based gas sensors

被引:40
作者
Degler, David [1 ]
Barz, Natascha [1 ]
Dettinger, Ulf [1 ]
Peisert, Heiko [1 ]
Chasse, Thomas [1 ]
Weimar, Udo [1 ]
Barsan, Nicolae [1 ]
机构
[1] Univ Tubingen, IPTC, D-72076 Tubingen, Germany
关键词
SnO2; Gas sensor; Operando spectroscopy; UV/vis; SENSING MATERIALS; SNO2; CO; MECHANISMS; SURFACE;
D O I
10.1016/j.snb.2015.10.040
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This work demonstrates the feasibility and benefit of operando UV/vis spectroscopy on SnO2-based gas sensors. The results on the different SnO2 sensing materials studied show an effect of the material's calcination temperature on the optical band gap and further indicate a dependence of the amount of reducible SnO2 on the grain size. To our knowledge this is the first report of a successful measurement of UV/vis spectra recorded from an operating gas sensor. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:256 / 259
页数:4
相关论文
共 21 条
[1]   Conduction model of metal oxide gas sensors [J].
Barsan, N ;
Weimar, U .
JOURNAL OF ELECTROCERAMICS, 2001, 7 (03) :143-167
[2]   Metal oxide-based gas sensor research: How to? [J].
Barsan, N. ;
Koziej, D. ;
Weimar, U. .
SENSORS AND ACTUATORS B-CHEMICAL, 2007, 121 (01) :18-35
[3]   Conduction mechanisms in SnO2 based polycrystalline thick film gas sensors exposed to CO and H2 in different oxygen backgrounds [J].
Barsan, N. ;
Huebner, M. ;
Weimar, U. .
SENSORS AND ACTUATORS B-CHEMICAL, 2011, 157 (02) :510-517
[4]   Surface studies of gas sensing metal oxides [J].
Batzill, Matthias ;
Diebold, Ulrike .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2007, 9 (19) :2307-2318
[5]   Surface science studies of gas sensing materials:: SnO2 [J].
Batzill, Matthias .
SENSORS, 2006, 6 (10) :1345-1366
[6]   ELECTRIC CONDUCTIVITY AND CATALYTIC ACTIVITY OF SEMICONDUCTING OXIDE CATALYSTS [J].
BIELANSKI, A ;
DEREN, J ;
HABER, J .
NATURE, 1957, 179 (4561) :668-679
[7]   Identifying the Active Oxygen Species in SnO2 Based Gas Sensing Materials: An Operando IR Spectrsocopy Study [J].
Degler, David ;
Wicker, Susanne ;
Weimar, Udo ;
Barsan, Nicolae .
JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (21) :11792-11799
[8]   Combined X-ray diffraction and diffuse reflectance analysis of nanocrystalline mixed Sn(II) and Sn(IV) oxide powders [J].
Deng, HM ;
Hossenlopp, JM .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (01) :66-73
[9]   Nanoparticle engineering for gas sensor optimisation:: improved sol-gel fabricated nanocrystalline SnO2 thick film gas sensor for NO2 detection by calcination, catalytic metal introduction and grinding treatments [J].
Diéguez, A ;
Romano-Rodríguez, A ;
Morante, JR ;
Kappler, J ;
Bârsan, N ;
Göpel, W .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 60 (2-3) :125-137
[10]   Growth, characterization, and properties of bulk SnO2 single crystals [J].
Galazka, Zbigniew ;
Uecker, Reinhard ;
Klimm, Detlef ;
Irmscher, Klaus ;
Pietsch, Mike ;
Schewski, Robert ;
Albrecht, Martin ;
Kwasniewski, Albert ;
Ganschow, Steffen ;
Schulz, Detlev ;
Guguschev, Christo ;
Bertram, Rainer ;
Bickermann, Matthias ;
Fornari, Roberto .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2014, 211 (01) :66-73