One-Pot Synthesis of Thiocarbamide Esters: Construction of C-S Bonds under Transition-Metal-Free Conditions

被引：0
|
作者：
Deng, Shi-Hao [1 ]
Yu, Jun-Xia [1 ]
Xiao, Hua-Qing [5 ]
Dong, Zhi-Bing [1 ,2 ,3 ,4 ]
机构：
[1] Wuhan Inst Technol, Sch Chem & Environm Engn, Wuhan 430205, Peoples R China
[2] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
[3] Henan Normal Univ, Sch Chem & Chem Engn, Xinxiang 453007, Peoples R China
[4] Wuhan Inst Technol, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Peoples R China
[5] Hubei Greenhome Mat Technol, Xiantao 433000, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 2022卷 / 46期
关键词：
C-S bond; One-Pot; Synthesis; Transition-Metal free; Thiocarbamide Esters; ARYLBORONIC ACIDS; THIOETHERS; CHLORIDES; DIARYL; THIOLS;
D O I：
10.1002/ejoc.202201167
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient and effective method for the construction of C-S bond under transition-metal free conditions was reported. Thus, diverse thiocarbamide esters could be smoothly obtained in moderate to good yields from inexpensive and readily available starting materials, such as phenyl isothiocyanate, alcohols and benzyl halides. This method features mild conditions, easy operation, short reaction time and broad substrate scopes, providing a facile and convenient strategy for the preparation of some compounds with potential biological activities.
引用
收藏
页数：4
相关论文
共 50 条
  • [31] Transition-Metal-Free Synthesis of Quinoxalines from o-Phenylenediamines and Arylacetaldehydes under Basic Conditions
    Song, Jinli
    Li, Xiaolong
    Chen, Yongxin
    Zhao, Mingming
    Dou, Yani
    Chen, Baohua
    SYNLETT, 2012, (16) : 2416 - 2420
  • [32] One-pot Metal-free Synthesis of Benzyl Alkyl Sulfides
    Lu, Xiaogang
    Wang, Hongmei
    Gao, Runli
    Pei, Chengxin
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2015, 190 (01) : 45 - 52
  • [33] TEMPO and its derivatives mediated reactions under transition-metal-free conditions
    Zhuang, Hongfeng
    Li, Heng
    Zhang, Shuai
    Yin, Yanbin
    Han, Feng
    Sun, Chao
    Miao, Chengxia
    CHINESE CHEMICAL LETTERS, 2020, 31 (01) : 39 - 48
  • [34] Transition-Metal-Free Direct Trifluoromethylation and Perfluoroalkylation of Imidazopyridines under Mild Conditions
    Han, Shuaijun
    Gao, Xianying
    Wu, Qingsong
    Li, Jingya
    Zou, Dapeng
    Wu, Yangjie
    Wu, Yusheng
    ADVANCED SYNTHESIS & CATALYSIS, 2019, 361 (07) : 1559 - 1563
  • [35] Solvent-free, one-pot synthesis of α,β-unsaturated esters in the presence of a C3-symmetric arsine
    Wang, Changqing
    Yang, Liu
    Zhou, Rong
    Mei, Guangquan
    SYNTHETIC COMMUNICATIONS, 2016, 46 (12) : 1074 - 1079
  • [36] Direct Conversion of Haloarenes to Phenols under Mild, Transition-Metal-Free Conditions
    Fier, Patrick S.
    Maloney, Kevin M.
    ORGANIC LETTERS, 2016, 18 (09) : 2244 - 2247
  • [37] Borate-mediated aryl polyfluoroalkoxylation under transition-metal-free conditions
    Kikushima, Kotaro
    Tsuda, Tomoka
    Miyamoto, Naoki
    Kita, Yasuyuki
    Dohi, Toshifumi
    CHEMICAL COMMUNICATIONS, 2024, 60 (76) : 10552 - 10555
  • [38] One-Pot Synthesis of Benzo[4,5]imidazo[1,2-a]quinazoline Derivatives via Facile Transition-Metal-Free Tandem Process
    Fang, Shuai
    Niu, Xiaoyi
    Yang, Bingchuan
    Li, Yanqiu
    Si, Xiaomeng
    Feng, Lei
    Ma, Chen
    ACS COMBINATORIAL SCIENCE, 2014, 16 (07) : 328 - 332
  • [39] One-Pot and Three-Component Synthesis of Furopyridoquinoxaline Derivatives under Catalyst-Free Conditions
    Zhang, Meimei
    Wang, Jie
    Liu, Jianquan
    Wang, Xiangshan
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2017, 37 (06) : 1565 - 1570
  • [40] One-pot synthesis of α-aminophosphonates on silica under solvent-free conditions from aromatic aldehydes
    Wu, Ming Shu
    Zhang, Xiang Zhu
    JOURNAL OF CHEMICAL RESEARCH, 2008, (10) : 562 - 563
12345