Simultaneous Adsorption and Degradation of Cr(VI) and Cd(II) Ions from Aqueous Solution by Silica-Coated Fe0 Nanoparticles

被引：4
|
作者：
Li, Yongchao [1 ]
Ma, Hongpu [1 ]
Ren, Bozhi [1 ]
Li, Tielong [2 ]
机构：
[1] Hunan Univ Sci & Technol, Sch Civil Engn, Xiangtan 411201, Peoples R China
[2] Nankai Univ, Coll Environm Sci & Engn, Tianjin 300071, Peoples R China
来源：
JOURNAL OF ANALYTICAL METHODS IN CHEMISTRY | 2013年 / 2013卷
基金：
中国国家自然科学基金;
关键词：
ZERO-VALENT IRON; REMOVAL; PB(II); CADMIUM; WATER; MICROSPHERES; SPECTROSCOPY; REMEDIATION; REDUCTION; CHEMISTRY;
D O I：
10.1155/2013/649503
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Core-shell silica-coated Fe-0 nanoparticles (Fe@SiO2) were prepared in one-step synthesis by aqueous reduction combined with modified Stober method. The as-prepared Fe@SiO2 were then used for simultaneous removal of Cr(VI) and Cd(II) from aqueous solution. Batch tests indicated that Fe@SiO2 exhibited high removal capacity toward Cr(VI) and Cd(II). Cr(VI) was removed by Fe@SiO2 through reduction rather than adsorption, while Cd(II) removal was mainly through adsorption. The removal rate increased with increasing initial Fe NPs dose and decreased with increasing initial Cr(VI) and Cd(II) concentrations. Cd(II) adsorption was also strengthened by Cr(VI) reduction with the release of OH-. The removals of Cr(VI) and Cd(II) were weakened in the presence of cations or humic acid, as a result of aggregation and less active site of Fe@SiO2. Overall, the simply prepared Fe@SiO2 were potential material for the heavy metals removed from water.
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页数：8
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