Highly efficient and selective oxidation of secondary alcohols to ketones under organic solvent and transition metal free conditions

被引：38
作者：
Jain, Suman L. [1 ]
Sharma, Vishal B. [1 ]
Sain, Bir [1 ]
机构：
[1] Indian Inst Petr, Chem & Biotechnol Div, Dehra Dun 248005, Uttar Pradesh, India
来源：
TETRAHEDRON | 2006年 / 62卷 / 29期
关键词：
oxidation; secondary alcohols; ketones; solid oxidant;
D O I：
10.1016/j.tet.2006.04.097
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The aqueous HBr/H2O2 was found to be highly efficient and green catalytic system for the selective oxidation of the secondary alcohols to ketones in excellent yields under organic solvent free conditions. The results of the oxidation of the secondary alcohols with solid alternatives of the aqueous hydrogen peroxide like SPC or SPB are also described. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6841 / 6847
页数：7
相关论文
共 41 条
[1]  
ALDRICH S, 2003, ALDRICH HDB FINE CHE
[2]   Selective oxidation of secondary alcohols [J].
Arterburn, JB .
TETRAHEDRON, 2001, 57 (49) :9765-9788
[3]  
BOUQUET F, 1948, B SOC CHIM FR, P1165
[4]  
Clark J. H., 2008, Handbook of Green Chemistry Technology
[5]   Cobalt(II)-catalyzed oxidation of alcohols into carboxylic acids and ketones with hydrogen peroxide [J].
Das, S ;
Punniyamurthy, T .
TETRAHEDRON LETTERS, 2003, 44 (32) :6033-6035
[6]  
ELVERS B, 1991, ULLMANNS ENCY IND A, V19, P117
[7]   Bromide ions and methyltrioxorhenium as cocatalysts for hydrogen peroxide oxidations and brominations [J].
Espenson, JH ;
Zhu, ZL ;
Zauche, TH .
JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (04) :1191-1196
[8]   Multiple bonds between transition metals and main-group elements Part 175 - The selective catalytic oxidation of terminal alcohols: a novel four-component system with MTO as catalyst [J].
Herrmann, WA ;
Zoller, JP ;
Fischer, RW .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 579 (1-2) :404-407
[9]  
Hudlicky M, 1990, ACS MONOGRAPH SER, V186
[10]  
Jones C.W., 1999, Applications of hydrogen peroxide and derivates
12345