Deep Oxidative Desulfurization of Fuel Oils Catalyzed by Decatungstates in the Ionic Liquid of [Bmim]PF6

被引：110

作者：

Li, Huaming ^{[1
,2
]}

Jiang, Xue ^{[1
]}

Zhu, Wenshuai ^{[1
]}

Lu, Jidong ^{[2
]}

Shu, Huoming ^{[1
]}

Yan, Yongsheng ^{[1
]}

机构：

[1] Jiangsu Univ, Coll Chem & Chem Engn, Zhenjiang 212013, Peoples R China

[2] Huazhong Univ Sci & Technol, State Key Lab Coal Combust, Wuhan 430074, Peoples R China

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2009年 / 48卷 / 19期

关键词：

EXTRACTIVE DESULFURIZATION; SELECTIVE OXIDATION; SOLVENT-EXTRACTION; EMULSION DROPLETS; SULFIDE OXIDATION; HYDROGEN-PEROXIDE; REFINERY STREAMS; DIESEL FUEL; H2O2; PEROXOTUNGSTEN;

D O I：

10.1021/ie900754f

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Three decatungstates with short carbon chains as the cations, such as tetrabutylammonium decatungstate ([(C4H9)(4)N](4)W10O32), tetramethylammonium decatungstate ([(CH3)(4)N](4)W10O32), and benzyltriethylammonium decatungstate ([(C2H5)(3)NC7H7](4)W10O32), Were synthesized and then used as a catalyst in the extractive catalytic oxidative desulfurization (ECODS) system in the ionic liquid (IL) of [Bmim]PF6, and hydrogen dioxide (H2O2) was used Lis an oxidant. During the optimized process, the Sulfur level in the model oil (1000 ppm S) can be reduced to 8 ppm, which is consistent with the Standards of deep desulfurization. The temperature, the reaction time, and the amount of H2O2 and catalyst, as well as the type of the cations of decatungstates, all played vital roles in desulfurization efficiency, which were studied in detail to optimize the reaction conditions. The system could be recycled five times before the sulfur removal decreased sharply.

引用

页码：9034 / 9039

页数：6

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