Metal-organic coordination architectures of tetrazole heterocycle ligands bearing acetate groups: Synthesis, characterization and magnetic properties

被引:4
|
作者
Hu, Bo-Wen [1 ]
Zheng, Xiang-Yu [1 ]
Ding, Cheng [1 ]
机构
[1] Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Peoples R China
基金
中国国家自然科学基金;
关键词
Tetrazole heterocycle ligands; Coordination architectures; Crystal structure; Magnetic properties; CRYSTAL-STRUCTURES; POLYMERS; FRAMEWORKS; COMPLEXES; AZIDE; CONSTRUCTION; DESIGN; ACID; TRANSFORMATION; ADSORPTION;
D O I
10.1016/j.jssc.2015.08.049
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Two new coordination complexes with tetrazole heterocycle ligands bearing acetate groups, [Co(L)(2)](n) (1) and [Co-3(L)(4)(N-3)(2)center dot 2MeOH](n) (2) (L=tetrazole-1-acetate) have been synthesized and structurally characterized. Single crystal structure analysis shows that the cobalt-complex 1 has the 3D 3,6-connected (4(2).6)(2)(4(4).6(2).8(8).10)-ant topology. By introducing azide in this system, complex 2 forms the 2D network containing the [Co-3] units. And the magnetic properties of 1 and 2 have been studied. (C) 2015 Elsevier Inc. All rights reserved.
引用
收藏
页码:62 / 66
页数:5
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