Lithographically organized 1D nano-tape arrays composed of solution processable above room temperature spin cross-over Fe(II) coordination polymer

被引：12

作者：

Botcha, Ajay Kumar ^{[1
]}

Basak, Supratim ^{[1
]}

Chandrasekar, Rajadurai ^{[1
]}

机构：

[1] Univ Hyderabad, Funct Mol Nanomicrosolids Lab, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

RSC ADVANCES | 2014年 / 4卷 / 66期

关键词：

IRON(II) COMPLEXES; MEMORY DEVICES; TRANSITION; HYSTERESIS; LIGANDS; FILM;

D O I：

10.1039/c4ra06726f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, highly soluble and solution processable Fe(II) spin cross-over (SCO) coordination polymer shows an SCO temperature at T-1/2 similar to 302 K. Bottom-up self-assembly of this supramolecular polymer in THF-water formed a several micron long nano-tape network. Further solution processing using a lithographically controlled wetting technique produced aligned 1D arrays of SCO nano-tape bundles.

引用

页码：34760 / 34763

页数：4

共 35 条

[11] Thin Deposits and Patterning of Room-Temperature-Switchable One-Dimensional Spin-Crossover Compounds [J].

Cavallini, Massimiliano ;

Bergenti, Ilaria ;

Milita, Silvia ;

Kengne, Jean Crispin ;

Gentili, Denis ;

Ruani, Giampiero ;

Salitros, Ivan ;

Meded, Velimir ;

Ruben, Mario .

LANGMUIR, 2011, 27 (07) :4076-4081

[12] An Iron(II) spin-transition compound with thiol anchoring groups [J].

Chandrasekar, Rajadurai ;

Schramm, Frank ;

Fuhr, Olaf ;

Ruben, Mario .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (17) :2649-2653

[13] Reversibly Shape-Shifting Organic Optical Waveguides: Formation of Organic Nanorings, Nanotubes, and Nanosheets [J].

Chandrasekhar, Naisa ;

Chandrasekar, Rajadurai .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (15) :3556-3561

[14] "Click-Fluors": Synthesis of a Family of π-Conjugated Fluorescent Back-to-Back Coupled 2,6-Bis(triazol-1-yl)pyridines and Their Self-Assembly Studies [J].

Chandrasekhar, Naisa ;

Chandrasekar, Rajadurai .

JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (14) :4852-4855

[15] Engineering self-assembled fluorescent organic nanotapes and submicrotubes from π-conjugated molecules [J].

Chandrasekhar, Naisa ;

Chandrasekar, Rajadurai .

CHEMICAL COMMUNICATIONS, 2010, 46 (17) :2915-2917

[16] Multilayer sequential assembly of thin films that display room-temperature spin crossover with hysteresis [J].

Cobo, Saioa ;

Molnar, Gabor ;

Real, Jose Antonio ;

Bousseksou, Azzedine .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (35) :5786-5789

[17] ELECTRONICS Inside story of ferroelectric memories [J].

Garcia, Vincent ;

Bibes, Manuel .

NATURE, 2012, 483 (7389) :279-281

[18] Tuning the spin-transition properties of pyrene-decorated 2,6-bispyrazolylpyridine based Fe(II) complexes [J].

Gonzalez-Prieto, Rodrigo ;

Fleury, Benoit ;

Schramm, Frank ;

Zoppellaro, Giorgio ;

Chandrasekar, Rajadurai ;

Fuhr, Olaf ;

Lebedkin, Sergei ;

Kappes, Manfred ;

Ruben, Mario .

DALTON TRANSACTIONS, 2011, 40 (29) :7564-7570

[19]

Halcrow M. A., 2013, SPIN CROSSOVER MAT P

[20] Structure:function relationships in molecular spin-crossover complexes [J].

Halcrow, Malcolm A. .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :4119-4142

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