Lithographically organized 1D nano-tape arrays composed of solution processable above room temperature spin cross-over Fe(II) coordination polymer

被引:12
作者
Botcha, Ajay Kumar [1 ]
Basak, Supratim [1 ]
Chandrasekar, Rajadurai [1 ]
机构
[1] Univ Hyderabad, Funct Mol Nanomicrosolids Lab, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
关键词
IRON(II) COMPLEXES; MEMORY DEVICES; TRANSITION; HYSTERESIS; LIGANDS; FILM;
D O I
10.1039/c4ra06726f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel, highly soluble and solution processable Fe(II) spin cross-over (SCO) coordination polymer shows an SCO temperature at T-1/2 similar to 302 K. Bottom-up self-assembly of this supramolecular polymer in THF-water formed a several micron long nano-tape network. Further solution processing using a lithographically controlled wetting technique produced aligned 1D arrays of SCO nano-tape bundles.
引用
收藏
页码:34760 / 34763
页数:4
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