Lithographically organized 1D nano-tape arrays composed of solution processable above room temperature spin cross-over Fe(II) coordination polymer

被引：12

作者：

Botcha, Ajay Kumar ^{[1
]}

Basak, Supratim ^{[1
]}

Chandrasekar, Rajadurai ^{[1
]}

机构：

[1] Univ Hyderabad, Funct Mol Nanomicrosolids Lab, Sch Chem, Hyderabad 500046, Andhra Pradesh, India

来源：

RSC ADVANCES | 2014年 / 4卷 / 66期

关键词：

IRON(II) COMPLEXES; MEMORY DEVICES; TRANSITION; HYSTERESIS; LIGANDS; FILM;

D O I：

10.1039/c4ra06726f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel, highly soluble and solution processable Fe(II) spin cross-over (SCO) coordination polymer shows an SCO temperature at T-1/2 similar to 302 K. Bottom-up self-assembly of this supramolecular polymer in THF-water formed a several micron long nano-tape network. Further solution processing using a lithographically controlled wetting technique produced aligned 1D arrays of SCO nano-tape bundles.

引用

页码：34760 / 34763

页数：4

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