Electrochemical pitting behaviour of type 321 stainless steel in sulfide-containing chloride solutions

The pitting behaviour of type 321 stainless steel in sulfide-containing chloride aqueous environments was studied using cyclic potentiodynamic polarization. A well-established correlation between H2S and Na2S2O3 in the study of corrosion was applied, that is, H2S was simulated by Na2S2O3. The major factors affecting the pitting corrosion of type 321 stainless steel are the Cl- concentration, solution pH and temperature. The results clearly indicate that both E-pit and E-pp decrease with increasing Cl- concentration and temperature, while I-pass is more sensitive to temperature variation. E-pit decreased with decreasing pH in the range 2 < pH < 7.5. The surface morphology and chemistry of the corroded type 321 stainless steel resulting from anodic polarization in 0.01 M S2O32--containing Cl- solution were analysed by XRD, SEM and EPMA. A higher concentration of sulfur was found in the pits, and the dark surface film was mainly composed of FeS and gamma-Fe2O3. The results describe the pitting behaviour of type 321 stainless steel in sulfide-containing Cl- aqueous environments.