Template synthesis of nanostructured silica with hollow core and mesoporous shell structures

被引:50
作者
Yoon, S. B.
Kim, J. Y.
Kim, J. H.
Park, S. G.
Kim, J. Y.
Lee, C. W.
Yu, J. -S. [1 ]
机构
[1] Hannam Univ, Dept Chem, Taejon 306791, South Korea
[2] LG Life & Hlth, Taejon 305600, South Korea
[3] KRICT, POX 107, Taejon 305600, South Korea
关键词
template; nanofabrication; hollow core and mesoporous shell; ORDERED MACROPOROUS MATERIALS; MOLECULAR-SIEVES; FABRICATION; CARBON; SPHERES;
D O I
10.1016/j.cap.2005.07.019
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Silica capsules with hollow macroporous core-mesoporous shell (HCMS) were synthesized through template-assisted replication of submicrometer-size polystyrene spheres as templates. The silica mesoporous shell exhibited highly ordered hexagonal structure as confirmed by X-ray diffraction pattern and TEM image. The pore diameter and BET surface area of this sample were found to be 2.1 nm and 1387 m(2)/g, respectively. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1059 / 1063
页数:5
相关论文
共 40 条
[1]  
Antonietti M, 1998, ADV MATER, V10, P154, DOI 10.1002/(SICI)1521-4095(199801)10:2<154::AID-ADMA154>3.0.CO
[2]  
2-I
[3]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[4]  
Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO
[5]  
2-N
[6]   Production of hollow microspheres from nanostructured composite particles [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
CHEMISTRY OF MATERIALS, 1999, 11 (11) :3309-3314
[7]   Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].
Caruso, F ;
Caruso, RA ;
Möhwald, H .
SCIENCE, 1998, 282 (5391) :1111-1114
[8]   Delaminated zeolite precursors as selective acidic catalysts [J].
Corma, A ;
Fornes, V ;
Pergher, SB ;
Maesen, TLM ;
Buglass, JG .
NATURE, 1998, 396 (6709) :353-356
[9]   STUDIES ON PREPARATION AND CHARACTERIZATION OF MONODISPERSE POLYSTYRENE LATTICES .3. PREPARATION WITHOUT ADDED SURFACE-ACTIVE AGENTS [J].
GOODWIN, JW ;
HEARN, J ;
HO, CC ;
OTTEWILL, RH .
COLLOID AND POLYMER SCIENCE, 1974, 252 (06) :464-471
[10]   Dual templating of macroporous silicates with zeolitic microporous frameworks [J].
Holland, BT ;
Abrams, L ;
Stein, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (17) :4308-4309