Bifunctional electrocatalysts for oxygen reduction/evolution reactions derived from NiCoFe LDH materials

被引：18

作者：

Oliver-Tolentino, M. ^{[1
]}

Vazquez-Samperio, J. ^{[2
]}

Tufino-Velazquez, M. ^{[3
]}

Flores-Moreno, J. ^{[4
]}

Lartundo-Rojas, L. ^{[5
]}

Gonzalez-Huerta, R. de G. ^{[1
]}

机构：

[1] ESIQIE IPN, Inst Politecn Nacl, Dept Ingn Quim, Lab Electroquim & Corros,GAM, UPALM Edif 7 PB Zacatenco, Mexico City 07738, DF, Mexico

[2] CICATA, Inst Politecn Nacl, Lab Nacl Convers & Almacenamiento Energia, Calzada Legaria 694, Mexico City 11500, DF, Mexico

[3] ESFM, Inst Politecn Nacl, Lab Fis Avanzada, UPALM Edif 9 Zacatenco, Mexico City 07738, DF, Mexico

[4] Univ Autonoma Metropolitana Azcapotzalco, Area Quim Mat, Av SanPablo180, Mexico City 02200, DF, Mexico

[5] UPALM, Inst Politecn Nacl, CNMN, GAM, Luis Enrique Erro S-N, Mexico City 07738, DF, Mexico

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2018年 / 48卷 / 08期

关键词：

Electrocatalysts; Spinel; Intermedia spin; Basicity; Oxygen reaction; LAYERED DOUBLE HYDROXIDES; NONSTOICHIOMETRIC CO3O4 FILMS; HIGH-SPIN CONFIGURATION; METAL-AIR BATTERIES; FERRITE SPINELS; ALKALINE MEDIA; REDUCTION; NICO2O4; CATALYSTS; EFFICIENT;

D O I：

10.1007/s10800-018-1210-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Materials obtained from thermal treatment of thermally treated NiCoFe-layered double hydroxides (LDH) with different Ni:Co ratios were evaluated as bifunctional catalysts for Oxygen Reduction Evolution and Evolution Reduction Reactions in alkaline media. The structural properties of synthesized materials were characterized by X-ray diffraction, Fourier-transform infrared, Raman, and X-ray photoelectron spectroscopies, whereas the basicity of each material was evaluated by temperature-programmed desorption of carbon dioxide. The results revealed the presence of inverse spinel structure with different compositions and a NiO phase with different amounts in the sample, while the electrochemical results showed a high activity towards oxygen reactions. The sample with higher amount of NiO and the lowest substitution grade on tetrahedral sites in the spinel-type structure exhibited the best catalytic activity. [GRAPHICS] .

引用

页码：947 / 957

页数：11

共 32 条

[21] Comparison of the Spinels Co3O4 and NiCo2O4 as Bifunctional Oxygen Catalysts in Alkaline Media [J].

Pletcher, Derek ;

Li, Xiaohong ;

Price, Stephen W. T. ;

Russell, Andrea E. ;

Soenmez, Turgut ;

Thompson, Stephen J. .

ELECTROCHIMICA ACTA, 2016, 188 :286-293

[22] Voltammetric Studies of the Mechanism of the Oxygen Reduction in Alkaline Media at the Spinels Co3O4 and NiCo2O4 [J].

Sonmez, Turgut ;

Thompson, Stephen J. ;

Price, Stephen W. T. ;

Pletcher, Derek ;

Russell, Andrea E. .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2016, 163 (10) :H884-H890

[23] Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal-air batteries [J].

Suntivich, Jin ;

Gasteiger, Hubert A. ;

Yabuuchi, Naoaki ;

Nakanishi, Haruyuki ;

Goodenough, John B. ;

Shao-Horn, Yang .

NATURE CHEMISTRY, 2011, 3 (07) :546-550

[24] Benchmark comparison of Co3O4 spinel-structured oxides with different morphologies for oxygen evolution reaction under alkaline conditions [J].

Videla, Alessandro H. A. Monteverde ;

Stelmachowski, Pawel ;

Ercolino, Giuliana ;

Specchia, Stefania .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2017, 47 (03) :295-304

[25] A Comparative Study of Composition and Morphology Effect of NixCo1-x(OH)2 on Oxygen Evolution/Reduction Reaction [J].

Wang, Lei ;

Lin, Chong ;

Huang, Dekang ;

Zhang, Fenging ;

Wang, Mingkui ;

Jin, Jian .

ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (13) :10172-10180

[26] Oxygen electrocatalysts in metal-air batteries: from aqueous to nonaqueous electrolytes [J].

Wang, Zhong-Li ;

Xu, Dan ;

Xu, Ji-Jing ;

Zhang, Xin-Bo .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (22) :7746-7786

[27] Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition-Metal Spinels [J].

Wei, Chao ;

Feng, Zhenxing ;

Scherer, Gunther G. ;

Barber, James ;

Shao-Horn, Yang ;

Xu, Zhichuan J. .

ADVANCED MATERIALS, 2017, 29 (23)

[28] Cation distribution and infrared properties of NixMn1-xFe2O4 ferrites [J].

Wei, QM ;

Li, JB ;

Chen, YJ .

JOURNAL OF MATERIALS SCIENCE, 2001, 36 (21) :5115-5118

[29] Three-Dimensional Macroporous NiCo2O4 Sheets as a Non-Noble Catalyst for Efficient Oxygen Reduction Reactions [J].

Xiao, Ying ;

Hu, Chuangang ;

Qu, Liangti ;

Hu, Changwen ;

Cao, Minhua .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (42) :14271-14278

[30] Nitrogen doped NiFe layered double hydroxide/reduced graphene oxide mesoporous nanosphere as an effective bifunctional electrocatalyst for oxygen reduction and evolution reactions [J].

Zhan, Tianrong ;

Liu, Xiaolin ;

Lu, Sisi ;

Hou, Wanguo .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2017, 205 :551-558

← 1 2 3 4 →