Bifunctional electrocatalysts for oxygen reduction/evolution reactions derived from NiCoFe LDH materials

被引：18
作者：
Oliver-Tolentino, M. [1 ]
Vazquez-Samperio, J. [2 ]
Tufino-Velazquez, M. [3 ]
Flores-Moreno, J. [4 ]
Lartundo-Rojas, L. [5 ]
Gonzalez-Huerta, R. de G. [1 ]
机构：
[1] ESIQIE IPN, Inst Politecn Nacl, Dept Ingn Quim, Lab Electroquim & Corros,GAM, UPALM Edif 7 PB Zacatenco, Mexico City 07738, DF, Mexico
[2] CICATA, Inst Politecn Nacl, Lab Nacl Convers & Almacenamiento Energia, Calzada Legaria 694, Mexico City 11500, DF, Mexico
[3] ESFM, Inst Politecn Nacl, Lab Fis Avanzada, UPALM Edif 9 Zacatenco, Mexico City 07738, DF, Mexico
[4] Univ Autonoma Metropolitana Azcapotzalco, Area Quim Mat, Av SanPablo180, Mexico City 02200, DF, Mexico
[5] UPALM, Inst Politecn Nacl, CNMN, GAM, Luis Enrique Erro S-N, Mexico City 07738, DF, Mexico
来源：
JOURNAL OF APPLIED ELECTROCHEMISTRY | 2018年 / 48卷 / 08期
关键词：
Electrocatalysts; Spinel; Intermedia spin; Basicity; Oxygen reaction; LAYERED DOUBLE HYDROXIDES; NONSTOICHIOMETRIC CO3O4 FILMS; HIGH-SPIN CONFIGURATION; METAL-AIR BATTERIES; FERRITE SPINELS; ALKALINE MEDIA; REDUCTION; NICO2O4; CATALYSTS; EFFICIENT;
D O I：
10.1007/s10800-018-1210-6
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Materials obtained from thermal treatment of thermally treated NiCoFe-layered double hydroxides (LDH) with different Ni:Co ratios were evaluated as bifunctional catalysts for Oxygen Reduction Evolution and Evolution Reduction Reactions in alkaline media. The structural properties of synthesized materials were characterized by X-ray diffraction, Fourier-transform infrared, Raman, and X-ray photoelectron spectroscopies, whereas the basicity of each material was evaluated by temperature-programmed desorption of carbon dioxide. The results revealed the presence of inverse spinel structure with different compositions and a NiO phase with different amounts in the sample, while the electrochemical results showed a high activity towards oxygen reactions. The sample with higher amount of NiO and the lowest substitution grade on tetrahedral sites in the spinel-type structure exhibited the best catalytic activity. [GRAPHICS] .
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收藏
页码：947 / 957
页数：11
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