Adsorption chemistry of sulfur dioxide in hydrated Na-Y zeolite

被引：14

作者：

Kirschhock, CEA ^{[1
]}

Sultana, A ^{[1
]}

Godard, E ^{[1
]}

Martens, JA ^{[1
]}

机构：

[1] Catholic Univ Louvain, Ctr Surface Chem & Catalysis, B-3001 Louvain, Belgium

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 28期

关键词：

environmental chemistry; nitrogen oxides; sulfur; X-ray diffraction; zeolites;

D O I：

10.1002/anie.200454266

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Exceptional resistance to sulfur poisoning of the Na-Y zeolite arises from the localization of adsorbed sulfur dioxide on the zeolite in the presence of water. The work shows that Rietveld refinement of guest molecules is a powerful method to determine positions and states of different molecules co-adsorbed on a zeolite (see picture; H2SO3 in yellow (S) and large red spheres (O); zeolite framework in small red (O) and gray (Si or Al) spheres; large gray sphere is the Na cation).

引用

页码：3722 / 3724

页数：3

共 50 条

[11] STRUCTURE AND TEXTURE OF A CRUSHED NA-Y ZEOLITE
MORAWECK, B
GALLEZOT, P
RENOUPRE.A
IMELIK, B
JOURNAL OF PHYSICAL CHEMISTRY, 1974, 78 (19): : 1959 - 1961
[12] Analytical theory of benzene diffusion in Na-Y zeolite
Auerbach, SM
JOURNAL OF CHEMICAL PHYSICS, 1997, 106 (18): : 7810 - 7815
[13] FAST HYDROTHERMAL AMMONIUM EXCHANGE OF ZEOLITE NA-Y
MAESEN, TLM
VANBEKKUM, H
VERBURG, TG
KOLAR, ZI
KOUWENHOVEN, HW
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (05): : 787 - 790
[14] NA-Y ZEOLITE, AN EFFICIENT CATALYST FOR THE METHOXYMETHYLATION OF ALCOHOLS
KUMAR, P
RAJU, SVN
REDDY, RS
PANDEY, B
TETRAHEDRON LETTERS, 1994, 35 (08) : 1289 - 1290
[15] Rotation of propane molecules in supercages of Na-Y zeolite
Mukhopadhyay, R
Sayeed, A
Rao, MN
Anilkumar, AV
Mitra, S
Yashonath, S
Chaplot, SL
CHEMICAL PHYSICS, 2003, 292 (2-3) : 217 - 222
[16] Modeling of NOx adsorption-desorption-reduction cycles on a ruthenium loaded Na-Y zeolite
Labaki, M.
Issa, M.
Smeekens, S.
Heylen, S.
Kirschhock, C. E. A.
Villani, K.
Jeguirim, M.
Habermacher, D.
Brilhac, J. F.
Martens, J. A.
APPLIED CATALYSIS B-ENVIRONMENTAL, 2010, 97 (1-2) : 13 - 20
[17] An investigation of the adsorption of aromatic hydrocarbons in zeolite Na-Y by solid-state NMR spectroscopy
Zhu, Jianfeng
Trefiak, Nick
Woo, Tom
Huang, Yining
MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 114 (1-3) : 474 - 484
[18] LOCATION AND MOLECULAR-MOTION OF HEXAMETHYLBENZENE IN ZEOLITE NA-Y
HONG, SB
CHO, HM
DAVIS, ME
JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (08): : 1629 - 1633
[19] Rotational dynamics of propylene inside Na-Y zeolite cages
V. K. Sharma
Mala N. Rao
Siddharth Gautam
A. K. Tripathi
V. S. Kamble
S. L. Chaplot
R. Mukhopadhyay
Pramana, 2008, 71 : 1165 - 1169
[20] VIBRATIONAL SPECTROSCOPY AND STRUCTURAL-ANALYSIS OF NA-Y ZEOLITE
RODRIGUEZ, A
VIBRATIONAL SPECTROSCOPY, 1995, 9 (02) : 225 - 228

← 1 2 3 4 5 →