Coordination of carboxamido nitrogen to tervalent iron: insight into a new chapter of iron chemistry

被引：125

作者：

Marlin, DS ^{[1
]}

Mascharak, PK ^{[1
]}

机构：

[1] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2000年 / 29卷 / 01期

关键词：

D O I：

10.1039/a905282h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Although coordination of carboxamido nitrogen to Fe(III) center has been assumed to be improbable, research work during the past few years has demonstrated that Fe(III) complexes with ligated carboxamido nitrogens can be readily synthesized. The Fe(III)-N-amido bond distances lie in the range of 1.8-2.2 Angstrom in the various low spin and high spin Fe(III) complexes. These complexes are stable in aqueous media and their redox parameters indicate that the carboxamido nitrogens provide significant stability to the Fe(III) center.

引用

页码：69 / 74

页数：6

共 24 条

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