Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: In situ photolysis, parahydrogen, and computational studies

被引：24

作者：

Ampt, Kirsten A. M. ^{[1
]}

Burling, Suzanne

Donald, Steven M. A.

Douglas, Susie

Duckett, Simon B.

Macgregor, Stuart A.

Perutz, Robin N.

Whittlesey, Michael K.

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England

[3] Heriot Watt Univ, Sch Engn & Phys Sci, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 23期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ja0622397

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Low-temperature UV irradiation of the N-heterocyclic carbene complex Ru(IEt2Me2)(PPh3)2(CO)H2 (IEt2Me2 = 1,3-bis(ethyl)-4,5-dimethylimidazol-2-ylidene) leads to a remarkable photoisomerization reaction. By combining in situ photolysis and parahydrogen experiments to characterize the ultimate photoproducts and DFT calculations to interrogate the structures of the key 16-electron intermediates, the importance of both PPh3 and H2 loss pathways has been established. Copyright © 2006 American Chemical Society.

引用

页码：7452 / 7453

页数：2

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