Self-assembly of amphiphilic nanoparticle-coil "tadpole" macromolecules

被引：54
|
作者：
Lee, JY
Balazs, AC [1 ]
Thompson, RB
Hill, RM
机构：
[1] Univ Pittsburgh, Dept Chem & Petr Engn, Pittsburgh, PA 15261 USA
[2] Los Alamos Natl Lab, Div Theoret, Los Alamos, NM 87545 USA
[3] Dow Corning Corp, Midland, MI 48686 USA
来源：
MACROMOLECULES | 2004年 / 37卷 / 10期
关键词：
D O I：
10.1021/ma035542q
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The equilibrium structure of a melt of amphiphilic 'tadpole' copolymers was investigated by using self-consistent field (SCF) and density functional theory (DFT) models. The tadpole copolymers were formed by attaching a flexible chain to a solid, nanoscopic headgroup. It was observed that the phase behavior of the tadpole copolymers differed significantly from that of compositionally comparable diblock copolymers. The results show that the addition of AB diblocks provides a way to control the overall morphology of the system and distribution of the particles within the materials.
引用
收藏
页码：3536 / 3539
页数：4
相关论文
共 50 条
  • [21] Synthesis and self-assembly in water of coil-rod-coil Amphiphilic block copolymers with central π-conjugated sequence
    de Cuendias, Anne
    Ibarboure, Emmanuel
    Lecommandoux, Sebastien
    Cloutet, Eric
    Cramail, Henri
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (13) : 4602 - 4616
  • [22] Synthesis and self-assembly of amphiphilic glycopolymers
    McRae, Michelle M.
    Foley, Olivia W.
    Goh, Sarah L.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 244
  • [23] Self-assembly of amphiphilic polymers.
    Lindman, B
    Alexandridis, P
    Olsson, U
    Piculell, L
    Thuresson, K
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 211 : 194 - COLL
  • [24] Synthesis and Self-assembly of Amphiphilic Homoglycopolypeptide
    Dhaware, Vinita
    Shaikh, Ashif Y.
    Kar, Mrityunjoy
    Hotha, Srinivas
    Sen Gupta, Sayam
    LANGMUIR, 2013, 29 (19) : 5659 - 5667
  • [25] Self-assembly of Amphiphilic Alternating Copolymers
    Xu, Qingsong
    Li, Shanlong
    Yu, Chunyang
    Zhou, Yongfeng
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (17) : 4255 - 4264
  • [26] Amphiphilic polymer self-assembly and disassembly
    Alexandridis, Paschalis
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [27] Self-assembly in amphiphilic spherical brushes
    Pu, Wan-Fen
    Ushakova, Alexandra
    Liu, Rui
    Lazutin, Alexei A.
    Vasilevskaya, Valentina V.
    JOURNAL OF CHEMICAL PHYSICS, 2020, 152 (23):
  • [28] Supramolecular Self-Assembly of Amphiphilic Calixarenes
    Liang Qing
    Guan Bing
    Jiang Ming
    PROGRESS IN CHEMISTRY, 2010, 22 (2-3) : 388 - 399
  • [29] Self-Assembly of Amphiphilic Cubes in Suspension
    Kobayashi, Yusei
    Nikoubashman, Arash
    LANGMUIR, 2022, 38 (34) : 10642 - 10648
  • [30] Imaging nanoparticle self-assembly
    Engineer, 2010, JANUARY
12345