Interior design engineering of CuS architecture alteration with rise in reaction bath temperature for high performance symmetric flexible solid state supercapacitor

被引:48
作者
Patil, A. M. [1 ]
Lokhande, A. C. [2 ]
Chodankar, N. R. [1 ]
Shinde, P. A. [1 ]
Kim, J. H. [2 ]
Lokhande, C. D. [1 ,3 ]
机构
[1] Shivaji Univ, Dept Phys, Thin Film Phys Lab, Kolhapur 416004, MS, India
[2] Chonnam Natl Univ, Dept Mat Sci & Engn, 300 Yongbong Dong, Gwangju, South Korea
[3] DY Patil Univ, Ctr Interdisciplinary Res, Kolhapur, Maharashtra, India
关键词
Chemical bath deposition; CuS nanoflowers; Polymer gel electrolyte; Symmetric flexible solid state supercapacitor; THIN-FILMS; NANOWIRE ARRAYS; SOLVOTHERMAL SYNTHESIS; DIFFERENT MORPHOLOGIES; ELECTRODE MATERIALS; ENERGY-STORAGE; COPPER SULFIDE; MICROSPHERES; NANOSHEETS; NANOCOMPOSITES;
D O I
10.1016/j.jiec.2016.10.019
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Present work portrays surface morphology alteration of CuS thin film with increase in reaction bath temperature. The porous nanoflowers like morphology of CuS offers higher electron transfer and shorten ion diffusion pathway, which facilitates transfer of electrolyte ions. Nanoflowers like morphology of CuS electrode exhibits specific capacitance (C-s) of 1818.2 F g(-1) at scan rate of 5 mV s(-1) with electrochemical cycling stability of 92%. The symmetric FSS-SCs-PVA-LiClO4 device demonstrates Cs of 172.5 F g(-1), specific power density of 1750 W kg(-1) and capacity retention of 93% after 2000 CV cycles. More importantly, this device glows the panel of 200 red LEDs. (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:91 / 102
页数:12
相关论文
共 55 条
[1]   Chemical synthesis of 3D copper sulfide with different morphologies for high performance supercapacitors application [J].
Bulakhe, Ravindra N. ;
Sahoo, Sumanta ;
Thi Toan Nguyen ;
Lokhande, Chandrakant D. ;
Roh, Changhyun ;
Lee, Yong Rok ;
Shim, Jae-Jin .
RSC ADVANCES, 2016, 6 (18) :14844-14851
[2]   Effect of different gel electrolytes on graphene-based solid-state supercapacitors [J].
Chen, Qiao ;
Li, Xinming ;
Zang, Xiaobei ;
Cao, Yachang ;
He, Yijia ;
Li, Peixu ;
Wang, Kunlin ;
Wei, Jinquan ;
Wu, Dehai ;
Zhu, Hongwei .
RSC ADVANCES, 2014, 4 (68) :36253-36256
[3]   Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].
Chen, Sheng ;
Zhu, Junwu ;
Wu, Xiaodong ;
Han, Qiaofeng ;
Wang, Xin .
ACS NANO, 2010, 4 (05) :2822-2830
[4]   Hierarchically mesoporous carbon nanopetal based electrodes for flexible supercapacitors with super-long cyclic stability [J].
Cherusseri, Jayesh ;
Kar, Kamal K. .
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (43) :21586-21598
[5]   Ionically conducting PVA-LiClO4 gel electrolyte for high performance flexible solid state supercapacitors [J].
Chodankar, Nilesh R. ;
Dubal, Deepak P. ;
Lokhande, Abhishek C. ;
Lokhande, Chandrakant D. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2015, 460 :370-376
[6]   Template-free and green sonochemical synthesis of hierarchically structured CuS hollow microspheres displaying excellent Fenton-like catalytic activities [J].
Deng, Chonghai ;
Ge, Xinqing ;
Hu, Hanmei ;
Yao, Li ;
Han, Chengliang ;
Zhao, Difang .
CRYSTENGCOMM, 2014, 16 (13) :2738-2745
[7]   Supercapacitive performance of hydrous ruthenium oxide (RuO2•nH2O) thin films deposited by SILAR method [J].
Deshmukh, P. R. ;
Pusawale, S. N. ;
Jagadale, A. D. ;
Lokhande, C. D. .
JOURNAL OF MATERIALS SCIENCE, 2012, 47 (03) :1546-1553
[8]   Effect of different modes of electrodeposition on supercapacitive properties of MnO2 thin films [J].
Dubal, D. P. ;
Dhawale, D. S. ;
Gujar, T. P. ;
Lokhande, C. D. .
APPLIED SURFACE SCIENCE, 2011, 257 (08) :3378-3382
[9]   Low-cost flexible supercapacitors with high-energy density based on nanostructured MnO2 and Fe2O3 thin films directly fabricated onto stainless steel [J].
Gund, Girish S. ;
Dubal, Deepak P. ;
Chodankar, Nilesh R. ;
Cho, Jun Y. ;
Gomez-Romero, Pedro ;
Park, Chan ;
Lokhande, Chandrakant D. .
SCIENTIFIC REPORTS, 2015, 5
[10]   Temperature influence on morphological progress of Ni(OH)2 thin films and its subsequent effect on electrochemical supercapacitive properties [J].
Gund, Girish S. ;
Dubal, Deepak P. ;
Jambure, Supriya B. ;
Shinde, Sujata S. ;
Lokhande, Chandrakant D. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (15) :4793-4803