Organosilanes in copper-mediated conjugate reductions and reductive aldol reactions

被引：54

作者：

Chiu, P ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2004年 / 13期

关键词：

organosilanes; copper conjugate reductions; aldol reactions;

D O I：

10.1055/s-2004-831172

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Organosilanes have been used to synthesize and regenerate copper hydrides, and have been employed as stoichiometric reductants in the copper-catalyzed reductions of a variety of activated olefins. Reductive aldol condensations and cyclizations using organosilanes and transition metal catalysts, including copper hydrides, have also been achieved.

引用

页码：2210 / 2215

页数：6

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