Organosilanes in copper-mediated conjugate reductions and reductive aldol reactions

被引：54
作者：
Chiu, P [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2004年 / 13期
关键词：
organosilanes; copper conjugate reductions; aldol reactions;
D O I：
10.1055/s-2004-831172
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Organosilanes have been used to synthesize and regenerate copper hydrides, and have been employed as stoichiometric reductants in the copper-catalyzed reductions of a variety of activated olefins. Reductive aldol condensations and cyclizations using organosilanes and transition metal catalysts, including copper hydrides, have also been achieved.
引用
收藏
页码：2210 / 2215
页数：6
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