Physicochemical Characterization of Miscanthus and its Application in Heavy Metals Removal from Wastewaters

被引:42
作者
Osman, Ahmed I. [1 ,2 ]
Ahmed, Abdelkader T. [3 ]
Johnston, Christopher R. [4 ]
Rooney, David W. [1 ]
机构
[1] Queens Univ Belfast, Sch Chem & Chem Engn, David Keir Bldg,Stranmillis Rd, Belfast BT9 5AG, Antrim, North Ireland
[2] South Valley Univ, Fac Sci Qena, Dept Chem, Qena 83523, Egypt
[3] Aswan Univ, Dept Civil Engn, Fac Engn, Aswan, Egypt
[4] AFBI, Hillsborough, North Ireland
关键词
miscanthus; wastewater; heavy metals removal; leaching properties; biomass; AQUEOUS-SOLUTIONS; FLY-ASH; PHYTOREMEDIATION; ADSORPTION; CAPACITY; BIOCHAR; DEHYDRATION; BIOSORPTION; TEMPERATURE; COMBUSTION;
D O I
10.1002/ep.12783
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Miscanthus species originated in Asia and were imported into Europe and North America as ornamental plants. They are perennial rhizomatous grasses with lignified stems and present very high growth rates, even in more temperate maritime climates. This potentially abundant biomass offers benefits to many sectors and is used to an extent in energy generation applications, however, issues with regards to its physicochemical combustion characteristics currently hinder this uptake. In this work, a novel alternative application, namely its direct use of dry miscanthus (DM) plant as an adsorbent for heavy metals removal (HMR) from wastewaters, was investigated. The physical, chemical, and leaching properties of DM were analyzed using XRD, SBET, TGA, DSC, SEM-EDX, elemental analysis, halogen, and ICP techniques. Subsequently, the HMR capacity of miscanthus was studied for lead, copper, and zinc from aqueous solutions. Results showed a high percentage removal of 66%, 83%, and 88%, respectively, with the majority being removed during the first hour of the test. Overall the results show that DM plant can be effectively utilized in wastewater treatment. (C) 2017 American Institute of Chemical Engineers
引用
收藏
页码:1058 / 1067
页数:10
相关论文
共 52 条
[1]   Role of sawdust in the removal of copper(II) from industrial wastes [J].
Ajmal, M ;
Khan, AH ;
Ahmad, S ;
Ahmad, A .
WATER RESEARCH, 1998, 32 (10) :3085-3091
[2]   Current status and future prospects of conversion of lignocellulosic resources to biofuels using yeasts and bacteria [J].
Alfenore, Sandrine ;
Molina-Jouve, Carole .
PROCESS BIOCHEMISTRY, 2016, 51 (11) :1747-1756
[3]   Low cost adsorbents for the removal of organic pollutants from wastewater [J].
Ali, Imran ;
Asim, Mohd. ;
Khan, Tabrez A. .
JOURNAL OF ENVIRONMENTAL MANAGEMENT, 2012, 113 :170-183
[4]  
ASTM, 2001, STAND TEST METH ASH
[5]  
ASTM, 2003, STAND TEST METH COMP, DOI [10.1520/E1131-03, DOI 10.1520/E1131-03]
[6]   Miscanthus: a fast-growing crop for biofuels and chemicals production [J].
Brosse, Nicolas ;
Dufour, Anthony ;
Meng, Xianzhi ;
Sun, Qining ;
Ragauskas, Arthur .
BIOFUELS BIOPRODUCTS & BIOREFINING-BIOFPR, 2012, 6 (05) :580-598
[7]   A unified correlation for estimating HHV of solid, liquid and gaseous fuels [J].
Channiwala, SA ;
Parikh, PP .
FUEL, 2002, 81 (08) :1051-1063
[8]   Metabolism of oxybenzone in a hairy root culture: Perspectives for phytoremediation of a widely used sunscreen agent [J].
Chen, Feiran ;
Huber, Christian ;
May, Robert ;
Schroeder, Peter .
JOURNAL OF HAZARDOUS MATERIALS, 2016, 306 :230-236
[9]   Kinetic study of the pyrolysis of miscanthus and its acid hydrolysis residue by thermogravimetric analysis [J].
Cortes, Ana Maria ;
Bridgwater, A. V. .
FUEL PROCESSING TECHNOLOGY, 2015, 138 :184-193
[10]   Biosorption of chromium species by aquatic weeds: Kinetics and mechanism studies [J].
Elangovan, R. ;
Philip, Ligy ;
Chandraraj, K. .
JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (01) :100-112