Various Synthetic Routes to a Gable-Like Bis(porphyrin) Constructed on a 1,10-Phenanthroline Chelate

被引：11

作者：

Beyler, Maryline ^{[1
]}

Beemelmanns, Christine ^{[1
]}

Heitz, Valerie ^{[1
]}

Sauvage, Jean-Pierre ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, Inst Chim, Lab Chim Organominerale,UMR 7177 LC3, F-67070 Strasbourg, France

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 2009卷 / 17期

关键词：

Synthesis design; Porphyrinoids; Cross-coupling; Macrocycles; PHOTOINDUCED ELECTRON-TRANSFER; BIS-PORPHYRIN; QUANTITATIVE FORMATION; COUPLING REACTION; ROTAXANES; BINDING; COMPLEX; MODEL; DIPYRROMETHANES; COORDINATION;

D O I：

10.1002/ejoc.200900149

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three different synthetic routes to obtain a gable-like bis(porphyrin) are described. The two porphyrins are covalently linked to a 2,9-diphenyl-1,10-phenanthroline chelate. One way to gain access to the bis(porphyrin) relies on the simultaneous construction of two porphyrins on a 2,9-bis(para-formylphenyl)-1,10-phenanthroline, whereas the other two are based on Suzuki cross-coupling reactions between a presynthesised porphyrin and an appropriate phenanthroline derivative. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2801 / 2805

页数：5

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