Environmentally friendly photoactive heterojunction zinc tin oxide nanoparticles

被引:23
作者
Ivetic, T. B. [1 ]
Fincur, N. L. [2 ]
Abramovic, B. F. [2 ]
Dimitrievska, M. [3 ]
Strbac, G. R. [1 ]
Cajko, K. O. [1 ]
Miljevic, B. B. [1 ]
Dacanin, Lj R. [1 ]
Lukic-Petrovic, S. R. [1 ]
机构
[1] Univ Novi Sad, Dept Phys, Fac Sci, Novi Sad 21000, Serbia
[2] Univ Novi Sad, Dept Chem Biochem & Environm Protect, Fac Sci, Novi Sad 21000, Serbia
[3] Catalonia Inst Energy Res IREC, Barcelona 08930, Spain
关键词
Powders: solid state reaction; Spectroscopy; Photodegradation; Amitriptyline; ENHANCED PHOTOCATALYTIC ACTIVITY; OPTICAL-PROPERTIES; ZNO NANOPARTICLES; DEGRADATION; ZNO-SNO2; NANOSTRUCTURES; WATER; NANOCOMPOSITES; ALPRAZOLAM; CATALYSTS;
D O I
10.1016/j.ceramint.2015.10.169
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Heterojunction zinc tin oxide (ZnO/SnO2) nanoparticles were prepared using a top down traditional solid-state method; mechanical grinding followed by annealing, and characterized by X-ray diffraction, multi-wavelength excitation Raman scattering, scanning electron microscopy, diffuse reflectance and photoluminescence spectroscopy. The photocatalytic degradation kinetics of amitriptyline in the presence of the obtained ZnO/SnO2 nanoparticles under simulated solar and UVA irradiation was determined and used as a model reaction for understanding the photocatalytic mechanism when such mixed oxide semiconductors are used in removing the pharmaceutically active compounds from wastewaters. (C) 2015 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:3575 / 3583
页数:9
相关论文
共 43 条
[1]   Mechanism of clomazone photocatalytic degradation: hydroxyl radical, electron and hole scavengers [J].
Abramovic, Biljana ;
Despotovic, Vesna ;
Sojic, Daniela ;
Fincur, Nina .
REACTION KINETICS MECHANISMS AND CATALYSIS, 2015, 115 (01) :67-79
[2]   Synthesized of nanophotocatalyst ZnO and ZnO doped with SnO2 and their application photochemical degradation a surfactant in aqueous solutions [J].
Akhgar, M. ;
Giahi, M. .
RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2015, 88 (06) :985-989
[3]   Composite Tin and Zinc oxide nanocrystalline particles for enhanced charge separation in sensitized degradation of dyes [J].
Bandara, J ;
Tennakone, K ;
Jayatilaka, PPB .
CHEMOSPHERE, 2002, 49 (04) :439-445
[4]   Psychiatric pharmaceuticals in the environment [J].
Calisto, Vania ;
Esteves, Valdemar I. .
CHEMOSPHERE, 2009, 77 (10) :1257-1274
[5]   Photocatalytic decolorization of methylene blue in aqueous solutions using coupled ZnO/SnO2 photocatalysts [J].
Chiang, Yu-Ju ;
Lin, Chia-Chang .
POWDER TECHNOLOGY, 2013, 246 :137-143
[6]   Temperature dependence of raman scattering in ZnO [J].
Cusco, Ramon ;
Alarcon-Llado, Esther ;
Ibanez, Jordi ;
Artus, Luis ;
Jimenez, Juan ;
Wang, Buguo ;
Callahan, Michael J. .
PHYSICAL REVIEW B, 2007, 75 (16)
[7]   Aerogel nanocomposites of ZnO-SnO2 as efficient photocatalysts for the degradation of rhodamine B [J].
Davis, Marauo ;
Hikal, Walid M. ;
Guemeci, Cenk ;
Hope-Weeks, Louisa J. .
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (05) :922-924
[8]   Enhanced photocatalytic activity of sulfur doped TiO2 for the decomposition of phenol: A new insight into the bulk and surface modification [J].
Devi, L. Gomathi ;
Kavitha, R. .
MATERIALS CHEMISTRY AND PHYSICS, 2014, 143 (03) :1300-1308
[9]   Raman scattering crystalline assessment of polycrystalline Cu2ZnSnS4 thin films for sustainable photovoltaic technologies: Phonon confinement model [J].
Dimitrievska, M. ;
Fairbrother, A. ;
Perez-Rodriguez, A. ;
Saucedo, E. ;
Izquierdo-Roca, V. .
ACTA MATERIALIA, 2014, 70 :272-280
[10]   Multiwavelength excitation Raman scattering study of polycrystalline kesterite Cu2ZnSnS4 thin films [J].
Dimitrievska, M. ;
Fairbrother, A. ;
Fontane, X. ;
Jawhari, T. ;
Izquierdo-Roca, V. ;
Saucedo, E. ;
Perez-Rodriguez, A. .
APPLIED PHYSICS LETTERS, 2014, 104 (02)