Transparent, conductive, and flexible carbon nanotube films and their application in organic light-emitting diodes

被引:914
作者
Zhang, Daihua
Ryu, Koungmin
Liu, Xiaolei
Polikarpov, Evgueni
Ly, James
Tompson, Mark E.
Zhou, Chongwu [1 ]
机构
[1] Univ So Calif, Dept EE Electrophys, Los Angeles, CA 90089 USA
[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA
关键词
D O I
10.1021/nl0608543
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have carried out comparative studies on transparent conductive thin films made with two kinds of commercial carbon nanotubes: HiPCO and arc-discharge nanotubes. These films have been further exploited as hole-injection electrodes for organic light-emitting diodes ( OLEDs) on both rigid glass and flexible substrates. Our experiments reveal that films based on arc-discharge nanotubes are overwhelmingly better than HiPCO-nanotube-based films in all of the critical aspects, including surface roughness, sheet resistance, and transparency. Further improvement in arc-discharge nanotube films has been achieved by using PEDOT passivation for better surface smoothness and using SOCl2 doping for lower sheet resistance. The optimized films show a typical sheet resistance of similar to 160 Omega/rectangle at 87% transparency and have been used successfully to make OLEDs with high stabilities and long lifetimes.
引用
收藏
页码:1880 / 1886
页数:7
相关论文
共 17 条
[1]   Electronic properties of single-walled carbon nanotube networks [J].
Bekyarova, E ;
Itkis, ME ;
Cabrera, N ;
Zhao, B ;
Yu, AP ;
Gao, JB ;
Haddon, RC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5990-5995
[2]   Purification and characterization of single-wall carbon nanotubes (SWNTs) obtained from the gas-phase decomposition of CO (HiPco process) [J].
Chiang, IW ;
Brinson, BE ;
Huang, AY ;
Willis, PA ;
Bronikowski, MJ ;
Margrave, JL ;
Smalley, RE ;
Hauge, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (35) :8297-8301
[3]   ALIGNED CARBON NANOTUBE FILMS - PRODUCTION AND OPTICAL AND ELECTRONIC-PROPERTIES [J].
DEHEER, WA ;
BACSA, WS ;
CHATELAIN, A ;
GERFIN, T ;
HUMPHREYBAKER, R ;
FORRO, L ;
UGARTE, D .
SCIENCE, 1995, 268 (5212) :845-847
[4]   Effect of SOCl2 treatment on electrical and mechanical properties of single-wall carbon nanotube networks [J].
Dettlaff-Weglikowska, U ;
Skákalová, V ;
Graupner, R ;
Jhang, SH ;
Kim, BH ;
Lee, HJ ;
Ley, L ;
Park, YW ;
Berber, S ;
Tománek, D ;
Roth, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (14) :5125-5131
[5]   Enhanced brightness in organic light-emitting diodes using a carbon nanotube composite as an electron-transport layer [J].
Fournet, P ;
Coleman, JN ;
Lahr, B ;
Drury, A ;
Blau, WJ ;
O'Brien, DF ;
Hörhold, HH .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (02) :969-975
[6]   A carbon nanotube composite as an electron transport layer for M3EH-PPV based light-emitting diodes [J].
Fournet, P ;
O'Brien, DF ;
Coleman, JN ;
Hörhold, HH ;
Blau, WJ .
SYNTHETIC METALS, 2001, 121 (1-3) :1683-1684
[7]   Fabrication and characterization of OLEDs using MEH-PPV and SWCNT nanocomposites [J].
Ha, YG ;
You, EA ;
Kim, BJ ;
Choi, JH .
SYNTHETIC METALS, 2005, 153 (1-3) :205-208
[8]   Purification and separation of carbon nanotubes [J].
Haddon, RC ;
Sippel, J ;
Rinzler, AG ;
Papadimitrakopoulos, F .
MRS BULLETIN, 2004, 29 (04) :252-259
[9]   Near-infrared electroluminescent devices using single-wall carbon nanotubes thin flms [J].
Kazaoui, S ;
Minami, N ;
Nalini, B ;
Kim, Y ;
Takada, N ;
Hara, K .
APPLIED PHYSICS LETTERS, 2005, 87 (21) :1-3
[10]   Characterization of light emitting devices based on a single-walled carbon nanotube-polymer composite [J].
Kim, JY ;
Kim, M ;
Choi, JH .
SYNTHETIC METALS, 2003, 139 (03) :565-568