catena-poly[[silver(I)-μ-1,4-bis(2-methyl-1H-imidazol-1-ylmethyl)benzene-κ2N3:N3′] nitrate]

被引：2
|
作者：
Dobrzanska, Liliana
Lloyd, Gareth O.
机构：
[1] Univ Stellenbosch, Dept Chem, ZA-7602 Matieland, South Africa
[2] Nicholas Copernicus Univ, Fac Chem, PL-87100 Torun, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2006年 / 62卷
关键词：
D O I：
10.1107/S1600536806023300
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, {[Ag(C16H18N4)]NO3}(n), the cationic part forms infinite chains where the Ag I ions are coordinated in a slightly bent fashion by two N-donor atoms of imidazole rings of two distinct ligand molecules. The nitrate anions interact weakly with the silver cations to form infinite strands running in the c-axis direction, approximately perpendicular to the cationic chains. The resulting layers are stabilized by offset pi-pi interactions between benzene rings. Furthermore, a set of C-(HO)-O-... and pi-pi interactions ( imidazole rings) between adjacent layers results in the formation of a three-dimensional assembly.
引用
收藏
页码：M1638 / M1640
页数：3
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