Solution Thermodynamics of Benzotriazole in Different Pure Solvents

被引：14

作者：

Luan, Yanan ^{[1
,2
]}

Li, Jing ^{[1
]}

Kaliwanda, Musika ^{[1
]}

Wang, Na ^{[1
]}

Chen, Kui ^{[1
]}

Li, Xin ^{[1
]}

Su, Weiyi ^{[3
]}

Hao, Hongxun ^{[1
,2
]}

机构：

[1] Tianjin Univ, Sch Chem Engn & Technol, Natl Engn Res Ctr Ind Crystallizat Technol, Tianjin 300072, Peoples R China

[2] Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

[3] Hebei Univ Technol, Sch Chem Engn, Tianjin 300130, Peoples R China

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2018年 / 63卷 / 05期

基金：

中国国家自然科学基金;

关键词：

VAPOR-LIQUID-EQUILIBRIUM; EXCESS MOLAR VOLUMES; BINARY-MIXTURES; FREE-ENERGY; 20; MPA; SOLUBILITY; PRESSURES; DENSITIES; METHANOL; ETHANOL;

D O I：

10.1021/acs.jced.7b01085

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Solubility data of benzotriazole (BTA) in 14 solvents were measured by a static gravimetric method from 268.15 to 303.15 K. The results illustrated that the solubility of BTA in N,N-dimethylacetamide is the highest whereas that in 1,2-dichloroethane is the lowest in all the tested solvents. And the values of solubility increase with increasing of temperature. Additionally, the modified Apelblat equation, the lambda h equation, the NRTL model, and the Wilson model were employed to correlate the experimental solubility data. It was found that all the selected thermodynamic models could give satisfactory correlation results. Furthermore, the thermodynamic properties of BTA during the dissolving process, including the enthalpy, the Gibbs energy, and the entropy, were also calculated and analyzed.

引用

页码：1546 / 1555

页数：10

共 37 条

[1] Corrosion of copper in BTA solutions - Effects of passive film removal [J].

Al-Hinai, AT ;

Osseo-Asare, K .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (05) :B23-B24

[2] Solubilities of o-acetylsalicylic, 4-aminosalicylic, 3,5-dinitrosalicylic, and p-toluic acid, and magnesium-DL-aspartate in water from T = (278 to 348) K [J].

Apelblat, A ;

Manzurola, E .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1999, 31 (01) :85-91

[3] P-ρ-T Data for 2-Butanol and tert-Butanol from 283.15 to 363.15 K and 303.15 to 363.15 K at Pressures up to 66 MPa [J].

Bravo-Sanchez, Micael G. ;

Guerrero-Zarate, David ;

Iglesias-Silva, Gustavo A. ;

Estrada-Baltazar, Alejandro .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2016, 61 (04) :1555-1565

[4] SOLVENT ACTIVITY ALONG A SATURATION LINE AND SOLUBILITY OF HYDROGEN-BONDING SOLIDS [J].

BUCHOWSKI, H ;

KSIAZCZAK, A ;

PIETRZYK, S .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (09) :975-979

[5] Heterobimetallic Ir-Sn catalysis: aza-Friedel-Crafts reaction of N-sulfonyl aldimines [J].

Chatterjee, Paresh Nath ;

Maity, Arnab Kumar ;

Mohapatra, Swapna Santa ;

Roy, Sujit .

TETRAHEDRON, 2013, 69 (13) :2816-2826

[6] Determination and Correlation of Solubility of Decahydropyrazino[2,3-b]pyrazine in Methanol, Ethanol, and 2-Propanol [J].

Chen, Jing ;

Zeng, Zuo-Xiang ;

Xue, Wei-Lan ;

Wang, Dan ;

Huang, Yu .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2011, 50 (20) :11755-11762

[7] Densities and Excess Molar Volumes of the Binary Mixtures of Cyclopentanone with Chloroalkanes at T = (288.15, 298.15, 308.15, and 318.15) K [J].

Ciocirlan, Oana ;

Teodorescu, Mariana ;

Dragoescu, Dana ;

Iulian, Olga ;

Barhala, Alexandru .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2010, 55 (09) :3891-3895

[8] LIQUID-PHASE EXCESS-ENTHALPIES FOR THE BINARY-MIXTURES OF 1-CHLORONAPHTHALENE + DICHLOROALKANES [J].

COMELLI, F ;

FRANCESCONI, R ;

KEHIAIAN, HV .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1991, 36 (04) :485-487

[9] EXCESS MOLAR VOLUMES OF ETHYLBENZENE AND (2-CHLOROETHYL)BENZENE+5 METHYL N-ALKYL KETONES AT 298.15-K [J].

COMELLI, F ;

FRANCESCONI, R .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1993, 38 (03) :450-452

[10]

Ficke L.E., 2010, Thermodynamic Properties of Imidazolium and Phosphonium Based Ionic Liquid Mixtures with Water or Carbon Dioxide

← 1 2 3 4 →