One-pot hydrothermal synthesis of Fe3O4/reduced graphene oxide nanocomposite for enhanced lithium storage

被引:0
作者
Zhang, Xiao [1 ]
Jiang, Bin [1 ]
Xie, Yaping [1 ]
Du, Feng [1 ]
机构
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China
来源
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2014年 / 53卷 / 03期
基金
中国国家自然科学基金;
关键词
Composites; Nanocomposites; Hydrothermal synthesis; Iron oxides; Reduced graphene oxide; Ferromagnetism; Lithium ion battery; ION BATTERIES; ANODE MATERIAL; FE3O4; NANOPARTICLES; FABRICATION; MICROSPHERES; ELECTRODES; CAPACITY; SPHERES; LI;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple one-pot hydrothermal approach is employed for the fabrication of Fe3O4/reduced graphene oxide (rGO) nanocomposite as the superior anode material for lithium ion batteries (LIB s). The reduction of graphene oxide sheets into rGO is achieved successfully during the hydrothermal process. The well-dispersed Fe3O4 nanoparticles are decorated on the surface of rGO sheets densely and homogeneously. With the introduction of rGO, the Fe3O4/rGO nanocomposite exhibits significant improvement in the reversible capability, cycling stability and rate performance in comparison with bare Fe3O4, delivering a high capacity of 884 mAh g(-1) at a current density of 200 mA g(-1) after 100 cycles. This hybrid composite is a potential candidate as anode material of high performance rechargeable lithium ion batteries.
引用
收藏
页码:265 / 273
页数:9
相关论文
共 36 条
[1]   Nanostructured Fe3O4/SWNT Electrode: Binder-Free and High-Rate Li-Ion Anode [J].
Ban, Chunmei ;
Wu, Zhuangchun ;
Gillaspie, Dane T. ;
Chen, Le ;
Yan, Yanfa ;
Blackburn, Jeffrey L. ;
Dillon, Anne C. .
ADVANCED MATERIALS, 2010, 22 (20) :E145-+
[2]   Nanomaterials for rechargeable lithium batteries [J].
Bruce, Peter G. ;
Scrosati, Bruno ;
Tarascon, Jean-Marie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (16) :2930-2946
[3]   L-Serine-Assisted Synthesis of Superparamagnetic Fe3O4 Nanocubes for Lithuium Ion Batteries [J].
Cao, Huaqiang ;
Liang, Renlong ;
Qian, Dong ;
Shao, Jin ;
Qu, Meizhen .
JOURNAL OF PHYSICAL CHEMISTRY C, 2011, 115 (50) :24688-24695
[4]   General synthesis of carbon-coated nanostructure Li4Ti5O12 as a high rate electrode material for Li-ion intercalation [J].
Cheng, Liang ;
Yan, Jing ;
Zhu, Guan-Nan ;
Luo, Jia-Yan ;
Wang, Cong-Xiao ;
Xia, Yong-Yao .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (03) :595-602
[5]   In situ XPS analysis of various iron oxide films grown by NO2-assisted molecular-beam epitaxy [J].
Fujii, T ;
de Groot, FMF ;
Sawatzky, GA ;
Voogt, FC ;
Hibma, T ;
Okada, K .
PHYSICAL REVIEW B, 1999, 59 (04) :3195-3202
[6]   Intrinsic peroxidase-like activity of ferromagnetic nanoparticles [J].
Gao, Lizeng ;
Zhuang, Jie ;
Nie, Leng ;
Zhang, Jinbin ;
Zhang, Yu ;
Gu, Ning ;
Wang, Taihong ;
Feng, Jing ;
Yang, Dongling ;
Perrett, Sarah ;
Yan, Xiyun .
NATURE NANOTECHNOLOGY, 2007, 2 (09) :577-583
[7]   An update on the reactivity of nanoparticles Co-based compounds towards Li [J].
Grugeon, S ;
Laruelle, S ;
Dupont, L ;
Tarascon, JM .
SOLID STATE SCIENCES, 2003, 5 (06) :895-904
[8]   One-pot synthesis of ferromagnetic Fe2.25W0.75O4 nanoparticles as a magnetically recyclable photocatalyst [J].
Guo, Jinxue ;
Zhou, Xiaoyu ;
Chen, Lei ;
Lu, Yibin ;
Zhang, Xiao ;
Hou, Wanguo .
JOURNAL OF NANOPARTICLE RESEARCH, 2012, 14 (07)
[9]   Lithium-ion intercalation Behavior of LiFePO4 in aqueous and nonaqueous electrolyte solutions [J].
He, Ping ;
Zhang, Xiao ;
Wang, Yong-Gang ;
Cheng, Liang ;
Xia, Yong-Yao .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (02) :A144-A150
[10]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339