Schiff base insertion in titanium alkyls; reduction of imine functions by benzyl addition

被引：0
|
作者：
Coles, SJ
Hursthouse, MB
Kelly, DG
Toner, AJ
Walker, NM
机构：
[1] Manchester Metropolitan Univ, Dept Chem & Mat, Manchester M1 5GD, Lancs, England
[2] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England
来源：
CANADIAN JOURNAL OF CHEMISTRY | 1999年 / 77卷 / 12期
关键词：
insertion; nucleophilic additions; Schiff bases; titanium;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
TiBz(4) reacts with N-2-fluorenyl(salicylideneimine) to afford a crystallographically characterized titanium(IV) complex containing two conventional bidentate Schiff base ligands and two O-bound ligands in which the imine function has been reduced by the addition of benzyl and hydrogen moieties.
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页码：2095 / 2098
页数：4
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