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Solvothermal synthesis of pompon-like nickel-cobalt hydroxide/graphene oxide composite for high-performance supercapacitor application
被引:42
|作者:
Lei, Xi
[1
]
Shi, Zheru
[1
]
Wang, Xiao
[1
]
Wang, Ting
[1
]
Ai, Jiebing
[1
]
Shi, Peiling
[1
]
Xue, Rui
[1
]
Guo, Hao
[1
]
Yang, Wu
[1
]
机构:
[1] Northwest Normal Univ, Key Lab Bioelectrochem & Environm Anal Gansu Prov, Coll Chem & Chem Engn, Lanzhou 730070, Gansu, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Nickel-cobalt double hydroxide;
Graphene oxide;
Supercapacitor;
Pseudocapacitance;
MICROWAVE-ASSISTED SYNTHESIS;
GRAPHENE OXIDE;
ASYMMETRIC SUPERCAPACITORS;
HYDROTHERMAL SYNTHESIS;
ELECTRODE MATERIALS;
HOLLOW MICROSPHERES;
NI FOAM;
CARBON;
NANOSHEETS;
POLYANILINE;
D O I:
10.1016/j.colsurfa.2018.04.011
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
Novel pompon-like nickel-cobalt double hydroxide/graphene oxide (Ni(OH)(2)/Co(OH)(2)/GO) composites were successfully synthesized via a simple one-step solvothermal process. Their structure, morphology, surface and electrochemical properties were characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM), X-ray diffraction(XRD), electrochemical impedance spectroscopy (EIS) and galvanostatic charge/discharge(GCD) curves. The composite electrodes showed typical pseudocapacitance performances. When addition amount of graphene oxide was 10 mg, resulted composite exhibited a high specific capacitance (2050.6 F g(-1) at 1 A g(-1)) and good cycling stability with a capacitance retention of 84% after 1000 cycles. Appropriate amount of graphene oxide not only served as a structural director but also enhanced the conductivity and stability of the resulted composite. The attractive performances and facile fabrication made the prepared Ni(OH)(2)/Co(OH)(2)/GO composite become a promising candidate for low-cost high-performance energy storage device.
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页码:76 / 85
页数:10
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