Photocatalytic alkoxy radical-mediated transformations

被引：120

作者：

Guo, Jing-Jing ^{[1
]}

Hu, Anhua ^{[1
]}

Zuo, Zhiwei ^{[1
]}

机构：

[1] ShanghaiTech Univ, Sch Phys Sci & Technol, Shanghai 201210, Peoples R China

来源：

TETRAHEDRON LETTERS | 2018年 / 59卷 / 22期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

Photoredox catalysis; Alkoxy radical; Hydrogen atom transfer; beta-Scission; C-H functionalization; VISIBLE-LIGHT PHOTOREDOX; C BOND FORMATION; ALPHA; BETA-EPOXY KETONES; SULFINIC ACIDS; HYDROGEN-ATOM; H BONDS; CATALYSIS; ALKENES; CLEAVAGE; FUNCTIONALIZATION;

D O I：

10.1016/j.tetlet.2018.04.060

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkoxy radicals have been intensively studied as versatile synthetic intermediates with well-established reactivity and selectivity. Due to the difficulties associated with the generation of these transient and high-energy radicals, the utilization of the unique reactivity of alkoxy radicals in catalytic platforms has become a rather challenging task. Recent studies on the alkoxy radical-mediated transformations have benefited tremendously from advances in modern photoredox catalysis. In this digest, we aim to highlight reported transformations that utilize alkoxy radicals in a photocatalytic fashion, in particular, underline novel catalytic platforms which we anticipate will find broad application in the near future. (C) 2018 Elsevier Ltd. All rights reserved.

引用

页码：2103 / 2111

页数：9

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