Direct Synthesis of 1,6-Hexanediol from HMF over a Heterogeneous Pd/ZrP Catalyst using Formic Acid as Hydrogen Source

被引：201

作者：

Tuteja, Jaya ^{[1
]}

Choudhary, Hemant ^{[1
]}

Nishimura, Shun ^{[1
]}

Ebitani, Kohki ^{[1
]}

机构：

[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan

来源：

CHEMSUSCHEM | 2014年 / 7卷 / 01期

关键词：

1,6-hexanediol; formic acid; heterogeneous catalysis; renewable resources; transfer hydrogenation; ONE-POT SYNTHESIS; SOLID ACID; LEVULINIC ACID; ZIRCONIUM-PHOSPHATES; FRUCTOSE; DEHYDRATION; BIOMASS; DECOMPOSITION; CONVERSION; OXIDATION;

D O I：

10.1002/cssc.201300832

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new approach is developed for hydrogenolytic ring opening of biobased 5-hydroxymethylfurfural (HMF), dehydration product of hexoses, towards 1,6-hexanediol (HDO) under atmospheric pressure. The highest yield of HDO, 43%, is achieved over reusable Pd/zirconium phosphate (ZrP) catalyst at 413 K in the presence of formic acid as hydrogen source. In comparison with various Bronsted and/or Lewis acidic supports, the specific Bronsted acidity on ZrP support effectively accelerated the cleavage of C-O bond in a furan ring.

引用

页码：96 / 100

页数：5

共 57 条

[1] Efficient oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran using Mn(III)-salen catalysts [J].

Amarasekara, Ananda S. ;

Green, Dalkeith ;

McMillan, Erinn .

CATALYSIS COMMUNICATIONS, 2008, 9 (02) :286-288

[2]

[Anonymous], 2010, ANGEW CHEM INT ED, V49, P6616

[3]

[Anonymous], 2011, ANGEW CHEM INT ED, V50, P7083

[4]

[Anonymous], ANGEW CHEM INT ED

[5] STUDY OF BENZENE HYDROGENATION AND IDENTIFICATION OF ADSORBED SPECIES WITH PT-AL2O3 CATALYSTS [J].

BASSET, JM ;

DALMAIIMELIK, G ;

PRIMET, M ;

MUTIN, R .

JOURNAL OF CATALYSIS, 1975, 37 (01) :22-36

[6] Bioenergy expansion in the EU: Cost-effective climate change mitigation, employment creation and reduced dependency on imported fuels [J].

Berndes, Goran ;

Hansson, Julia .

ENERGY POLICY, 2007, 35 (12) :5965-5979

[7] Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions [J].

Bi, Qng-Yuan ;

Du, Xian-Long ;

Liu, Yong-Mei ;

Cao, Yong ;

He, He-Yong ;

Fan, Kang-Nian .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (21) :8926-8933

[8] Dehydration of fructose to 5-hydroxymethylfurfural in sub- and supercritical acetone [J].

Bicker, M ;

Hirth, J ;

Vogel, H .

GREEN CHEMISTRY, 2003, 5 (02) :280-284

[9] Efficient Dehydrogenation of Formic Acid Using an Iron Catalyst [J].

Boddien, Albert ;

Mellmann, Doerthe ;

Gaertner, Felix ;

Jackstell, Ralf ;

Junge, Henrik ;

Dyson, Paul J. ;

Laurenczy, Gabor ;

Ludwig, Ralf ;

Beller, Matthias .

SCIENCE, 2011, 333 (6050) :1733-1736

[10] Selective dehydrogenation of cyclohexene to benzene using Pd-exchanged alpha-zirconium phosphate [J].

Borade, RB ;

Zhang, B ;

Clearfield, A .

CATALYSIS LETTERS, 1997, 45 (3-4) :233-235

← 1 2 3 4 5 6 →