Hyperbranched Polymers for Photolithographic Applications - Towards Understanding the Relationship between Chemical Structure of Polymer Resin and Lithographic Performances

被引:40
作者
Chochos, Christos L. [1 ]
Ismailova, Esma [1 ]
Brochon, Cyril [1 ]
Leclerc, Nicolas [1 ]
Tiron, Raluca [2 ]
Sourd, Claire [2 ]
Bandelier, Philippe [2 ]
Foucher, Johann [2 ]
Ridaoui, Hassan [3 ]
Dirani, Ali [3 ]
Soppera, Olivier [3 ]
Perret, Damien [4 ]
Brault, Christophe [4 ]
Serra, Christophe A. [1 ]
Hadziioannou, Georges [1 ]
机构
[1] Univ Strasbourg, Ecole Europeenne Chim Polymeres & Mat, Lab Ingn Polymeres Hautes Technol, UMR 7165, F-67087 Strasbourg, France
[2] CEA Leti Minatec, Lithog Lab, F-38054 Grenoble, France
[3] Univ Haute Alsace, UMR 7525, CNRS, Dept Photochim Gen, F-68058 Mulhouse, France
[4] CEA Grenoble, Rohm & Haas Elect Mat, F-38054 Grenoble 9, France
关键词
RADICAL POLYMERIZATION; RAFT POLYMERIZATION; AMPLIFICATION; COPOLYMERS; MONOLAYERS;
D O I
10.1002/adma.200801715
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A chemically amplified resist based on a hyperbranched polymer resin is demonstrated for the first time. The hyperbranched polymer is synthesized using the atom-transfer radical polymerization (ATRP) technique, and resists prepared from this hyperbranched polymer present good pattern profiles and line-edge roughness (3 sigma) values comparable to those of the reference (commercial) resist.
引用
收藏
页码:1121 / 1125
页数:5
相关论文
共 37 条
[1]   Asymmetric synthesis of arylpropionic acids and aryloxy acids by using lactamides as chiral auxiliaries [J].
Ammazzalorso, Alessandra ;
Amoroso, Rosa ;
Bettoni, Giancarlo ;
De Filippis, Barbara ;
Fantacuzzi, Marialuigia ;
Giampietro, Letizia ;
Maccallini, Cristina ;
Tricca, Maria L. .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 2006 (18) :4088-4091
[2]   ATOMIC FORCE MICROSCOPE [J].
BINNIG, G ;
QUATE, CF ;
GERBER, C .
PHYSICAL REVIEW LETTERS, 1986, 56 (09) :930-933
[3]  
BOWDEN MJ, 1988, ADV CHEM SER, V218, P1
[4]   Controlled/living radical polymerization: Features, developments, and perspectives [J].
Braunecker, Wade A. ;
Matyjaszewski, Krzysztof .
PROGRESS IN POLYMER SCIENCE, 2007, 32 (01) :93-146
[5]   Thiocarbonylthio compounds [S=C(Ph)S-R] in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization). Role of the free-radical leaving group (R) [J].
Chong, YK ;
Krstina, J ;
Le, TPT ;
Moad, G ;
Postma, A ;
Rizzardo, E ;
Thang, SH .
MACROMOLECULES, 2003, 36 (07) :2256-2272
[6]   Effect of polymer molecular weight on AFM polymer aggregate size and LER of EUV resists [J].
Cutler, CA ;
Mackevich, JF ;
Li, JM ;
O'Connell, DJ ;
Cardinale, G ;
Brainard, RL .
EMERGING LITHOGRAPHIC TECHNOLOGIES VII, PTS 1 AND 2, 2003, 5037 :406-417
[7]   Tip characterization and surface reconstruction of complex structures with critical dimension atomic force microscopy [J].
Dahlen, G ;
Osborn, M ;
Okulan, N ;
Foreman, W ;
Chand, A ;
Foucher, J .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2005, 23 (06) :2297-2303
[8]  
DAHLEN G, 2007, P SPIE MICROLITHOGRA, V6518, P65181
[9]   Dimensions and shapes of block copolymer domains assembled on lithographically defined chemically patterned substrates [J].
Edwards, Erik W. ;
Mueller, Marcus ;
Stoykovich, Mark P. ;
Solak, Harun H. ;
de Pablo, Juan J. ;
Nealey, Paul F. .
MACROMOLECULES, 2007, 40 (01) :90-96
[10]   Plasma-surface interactions of model polymers for advanced photoresists using C4F8/Ar discharges and energetic ion beams [J].
Engelmann, S. ;
Bruce, R. L. ;
Kwon, T. ;
Phaneuf, R. ;
Oehrlein, G. S. ;
Bae, Y. C. ;
Andes, C. ;
Graves, D. ;
Nest, D. ;
Hudson, E. A. ;
Lazzeri, P. ;
Lacob, E. ;
Anderle, M. .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2007, 25 (04) :1353-1364