Hydrothermal synthesis and crystal structure of a novel 4,4′-bipyridine bridging dumbbell-like dimeric pentamolybdate:: [4,4′-H2bipy]3[4,4′-Hbipy]2[(Mo5O17)2(4,4′-bipy)]

被引:9
|
作者
Niu, JY [1 ]
Wang, ZL [1 ]
Wang, JP [1 ]
机构
[1] Henan Univ, Sch Chem & Chem Engn, Kaifeng 475001, Peoples R China
关键词
polyoxometalates; hydrothermal synthesis; crystal structure; molybdenum;
D O I
10.1016/j.inoche.2004.02.018
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel dimeric pentamolybdate [4,4'-H(2)bipy](3)[4,4'-Hbipy](2)[(Mo5O17)(2)(4,4'-bipy)], the first example of a 4,4'-bipyridine bridging dumbbell-like polyoxomolybdates, has been prepared by hydrothermal synthesis and characterized by X-ray crystallography. (C) 2004 Elsevier B.V. All rights reserved.
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页码:556 / 558
页数:3
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