Two Redox Couples are Better Than One: Improved Current and Fill Factor from Cobalt-Based Electrolytes in Dye-Sensitized Solar Cells

被引：13

作者：

Cong, Jiayan ^{[1
]}

Hao, Yan ^{[2
]}

Sun, Licheng ^{[3
,4
]}

Kloo, Lars ^{[1
]}

机构：

[1] KTH Royal Inst Technol, Dept Chem, Sch Chem Sci & Engn, S-10044 Stockholm, Sweden

[2] Uppsala Univ, Dept Chem, Angstrom Lab, S-75120 Uppsala, Sweden

[3] KTH Royal Inst Technol, Dept Chem, Sch Chem Sci & Engn, S-10044 Stockholm, Sweden

[4] Dalian Univ Technol, DUT KTH Joint Educ & Res Ctr Mol Devices, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

ADVANCED ENERGY MATERIALS | 2014年 / 4卷 / 08期

基金：

瑞典研究理事会;

关键词：

RUTHENIUM SENSITIZERS; MASS-TRANSPORT; TIO2; FILMS; EFFICIENCY; MEDIATOR;

D O I：

10.1002/aenm.201301273

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A tandem redox strategy is used in cobalt-based electrolytes. Co(bpy) 32+/Co(bpy)33+ offers a high photovoltage at the photoanode, whereas the I-/I3 - or Fc/Fc+ redox couples facilitate charge transfer at the counter electrode. Electron exchange in the electrolyte offers beneficial concentration gradients. The overall conversion efficiency is improved from 6.5% to 7.5%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页数：6

共 45 条

[1] Cobalt-Based Electrolytes for Efficient Flexible Dye-Sensitized Solar Cells
Kim, Jihun
Lee, Horim
Kim, Dong Young
Kim, Sehyun
Seo, Yongsok
MRS ADVANCES, 2019, 4 (08) : 481 - 489
[2] Reduced graphene oxide catalysts for efficient regeneration of cobalt-based redox electrolytes in dye-sensitized solar cells
Giannouri, Maria
Bidikoudi, Maria
Pastrana-Martinez, Luisa M.
Silva, Adrian M. T.
Falaras, Polycarpos
ELECTROCHIMICA ACTA, 2016, 219 : 258 - 266
[3] Fabrication and Characterization of Bifacial Dye-Sensitized Solar Cells Utilizing Indoline Dye with Iodine- and Cobalt-Based Redox Electrolytes
Shaban, Suraya
Pradhan, Safalmani
Pandey, Shyam S.
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2023, 220 (24):
[4] Mesoporous TiO2 Beads Offer Improved Mass Transport for Cobalt-Based Redox Couples Leading to High Efficiency Dye-Sensitized Solar Cells
Heiniger, Leo-Philipp
Giordano, Fabrizio
Moehl, Thomas
Graetzel, Michael
ADVANCED ENERGY MATERIALS, 2014, 4 (12)
[5] The effect of dye coverage on the performance of dye-sensitized solar cells with a cobalt-based electrolyte
Pazoki, Meysam
Lohse, Peter William
Taghavinia, Nima
Hagfeldt, Anders
Boschloo, Gerrit
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (18) : 8503 - 8508
[6] The Effect of the Scattering Layer in Dye-Sensitized Solar Cells Employing a Cobalt-Based Aqueous Gel Electrolyte
Xiang, Wanchun
Chen, Dehong
Caruso, Rachel A.
Cheng, Yi-Bing
Bach, Udo
Spiccia, Leone
CHEMSUSCHEM, 2015, 8 (21) : 3704 - 3711
[7] Multiple linker half-squarylium dyes for dye-sensitized solar cells; are two linkers better than one?
Connell, Arthur
Holliman, Peter J.
Jones, Eurig W.
Furnell, Leo
Kershaw, Christopher
Davies, Matthew L.
Gwenin, Christopher D.
Pitak, Mateusz B.
Coles, Simon J.
Cooke, Graeme
JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (06) : 2883 - 2894
[8] Aqueous dye-sensitized solar cell electrolytes based on the cobalt(II)/(III) tris(bipyridine) redox couple
Xiang, Wanchun
Huang, Fuzhi
Cheng, Yi-Bing
Bach, Udo
Spiccia, Leone
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (01) : 121 - 127
[9] Tridentate cobalt complexes as alternative redox couples for high-efficiency dye-sensitized solar cells
Ben Aribia, Kais
Moehl, Thomas
Zakeeruddin, Shaik M.
Graetzel, Michael
CHEMICAL SCIENCE, 2013, 4 (01) : 454 - 459
[10] Transparent Conductive Oxide-Less Dye-Sensitized Solar Cells Consisting of Dye-Cocktail and Cobalt Based Redox Electrolyte
Molla, Md. Zaman
Baranwal, Ajay K.
Pandey, Shyam S.
Ma, Tingli
Hayase, Shuzi
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2017, 17 (07) : 4748 - 4754

← 1 2 3 4 5 →