Study of a polymer immobilized on silica gel as stationary phase for chiral liquid chromatography

被引:11
作者
Guillaume, M
Sebille, B
机构
[1] Lab. de Physchim. des Biopolymeres, UMR 27 CNRS-Univ. Paris XII, F-94320 Thiais
关键词
D O I
10.1016/0014-3057(95)00120-4
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The adsorption of beta-cyclodextrin polymer was studied on different silica beads, in water-organic solvent mixtures. A maximum adsorption on Lichrospher 100 Angstrom 5 mu m was observed for a polymer solution containing 70% acetone. Different crosslinking agents were used to stabilize the polymer layer on the silica surface to make a convenient support for liquid chromatography. Glutaraldehyde appeared as very efficient for this purpose and enabled chiral supports to be prepared.
引用
收藏
页码:19 / 26
页数:8
相关论文
共 35 条
[1]  
[Anonymous], STARCH
[2]   A NOVEL POLYVIOLOGEN ELECTRODE FABRICATED BY ELECTROCHEMICAL CROSS-LINKING [J].
CHANG, HC ;
OSAWA, M ;
MATSUE, T ;
UCHIDA, I .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (09) :611-612
[3]   CLASSIFICATION OF THE SOLUBILITY BEHAVIOR OF BETA-CYCLODEXTRIN IN AQUEOUS COSOLVENT MIXTURES [J].
COLEMAN, AW ;
MUNOZ, M ;
CHATJIGAKIS, AK ;
CARDOT, P .
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1993, 6 (12) :651-659
[4]   INTERACTION BETWEEN ASYMMETRIC SOLUTES AND SOLVENTS - N-LAUROYL-L-VALYL TERT BUTYLAMIDE AS STATIONARY PHASE IN GAS LIQUID PARTITION CHROMATOGRAPHY [J].
FEIBUSH, B .
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (11) :544-&
[5]  
GILAV E, 1966, TETRAHEDRON LETT, P1009
[6]   THIN-LAYER CHROMATOGRAPHIC-SEPARATION OF ORTHO, META, AND PARA-SUBSTITUTED BENZOIC-ACIDS AND PHENOLS WITH AQUEOUS-SOLUTIONS OF ALPHA-CYCLODEXTRIN [J].
HINZE, WL ;
ARMSTRONG, DW .
ANALYTICAL LETTERS PART A-CHEMICAL ANALYSIS, 1980, 13 (12) :1093-1104
[7]   LIQUID-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS USING A CHIRAL BETA-CYCLODEXTRIN-BONDED STATIONARY PHASE AND CONVENTIONAL AQUEOUS ORGANIC MOBILE PHASES [J].
HINZE, WL ;
RIEHL, TE ;
ARMSTRONG, DW ;
DEMOND, W ;
ALAK, A ;
WARD, T .
ANALYTICAL CHEMISTRY, 1985, 57 (01) :237-242
[8]   (1S,2R)-N-(3,5-DINITROBENZOYL) NOREPHEDRINE BONDED TO SILICA-GEL AS A CHIRAL STATIONARY PHASE FOR THE LIQUID-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERS [J].
HYUN, MH ;
KIM, MH .
JOURNAL OF LIQUID CHROMATOGRAPHY, 1990, 13 (16) :3229-3243
[9]  
KANDRA L, 1984, J INCLUSION PHENOM, V2, P869
[10]  
KONIG WA, 1990, HRC-J HIGH RES CHROM, V13, P702