Atom-Efficient Vinylic Arylations with Triarylbismuths as Substoichiometric Multicoupling Reagents under Palladium Catalysis

被引：35

作者：

Rao, Maddali L. N. ^{[1
]}

Jadhav, Deepak N. ^{[1
]}

Venkatesh, Varadhachari ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 2009卷 / 25期

关键词：

Arylation; Bismuth; Palladium; Atom efficiency; Cross-coupling; CROSS-COUPLING REACTIONS; GRIGNARD-REAGENTS; ORGANOBISMUTH DIALKOXIDES; ARYLBORONIC ACIDS; ORGANIC-SYNTHESIS; FACILE SYNTHESIS; ACYL CHLORIDES; ARYL BROMIDES; TIN REAGENTS; HALIDES;

D O I：

10.1002/ejoc.200900487

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first atom-efficient arylation of vinylic iodides was achieved by using triarylbismuths as substoichiometric multicoupling reagents under palladium catalysis. Vinylic iodides were efficiently coupled with electronically divergent triarylbismuths to furnish the corresponding arylated products in short reaction times. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：4300 / 4306

页数：7

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