First observation of electron paired with divalent and trivalent nonreactive metal cations in water

被引：19

作者：

Bonin, J ^{[1
]}

Lampre, I ^{[1
]}

Soroushian, B ^{[1
]}

Mostafavi, M ^{[1
]}

机构：

[1] Univ Paris 11, UMR 8000, CNRS, Lab Chim Phys,ELYSE,Ctr Orsay, F-91405 Orsay, France

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2004年 / 108卷 / 33期

关键词：

D O I：

10.1021/jp047492c

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effects of several chloride and perchlorate salts (NH4+, Na+, Mg2+, Tb3+) at high concentration in water on the optical absorption spectrum of the hydrated electron are studied. For a given salt, the hydrated electron spectrum shifts toward high energy as the salt concentration is increased. For the same chloride salt concentration, the blue shift of the hydrated electron spectrum increases with the charge of the cation, the largest corresponding to the pair formed with Tb3+, studied for the first time.

引用

页码：6817 / 6819

页数：3

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