Proton migration on the [60]fullerene cage of 1-tert-butyl-1,4-dihydro[60]fullerene to yield the 1,2-isomer

被引:12
作者
Banim, F
Cardin, DJ
Heath, P
机构
[1] Department of Chemistry, University of Reading, Reading Berkshire, RG6 6AD, Whiteknights
关键词
D O I
10.1039/a605859k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Proton NMR data on the base catalysed rearrangement of 1-tert-butyl-1,4-dihydro[60]fullerene to the 1,2-isomer reveal a second order reaction and an activation energy of 56.1 kJ mol(-1).
引用
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页码:25 / 26
页数:2
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