Microstructure and properties of Ag-Ti3SiC2 contact materials prepared by pressureless sintering

被引:30
作者
Zhang, Min [1 ]
Tian, Wu-bian [1 ]
Zhang, Pei-gen [1 ]
Ding, Jian-xiang [1 ]
Zhang, Ya-mei [2 ]
Sun, Zheng-ming [1 ]
机构
[1] Southeast Univ, Sch Mat Sci & Engn, Jiangsu Key Lab Adv Metall Mat, Nanjing 211189, Jiangsu, Peoples R China
[2] Southeast Univ, Sch Mat Sci & Engn, Jiangsu Key Lab Construct Mat, Nanjing 211189, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
MAX phase; Ag-Ti3SiC2; contact materials; wettability; pressureless sintering; MECHANICAL-PROPERTIES; TI3SIC2; COMPOSITES; TI3ALC2; CU; TEMPERATURE; FABRICATION; POWDERS; STABILITY; BEHAVIOR;
D O I
10.1007/s12613-018-1629-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ti3SiC2-reinforced Ag-matrix composites are expected to serve as electrical contacts. In this study, the wettability of Ag on a Ti3SiC2 substrate was measured by the sessile drop method. The Ag-Ti3SiC2 composites were prepared from Ag and Ti3SiC2 powder mixtures by pressureless sintering. The effects of compacting pressure (100-800 MPa), sintering temperature (850-950A degrees C), and soaking time (0.5-2 h) on the microstructure and properties of the Ag-Ti3SiC2 composites were investigated. The experimental results indicated that Ti3SiC2 particulates were uniformly distributed in the Ag matrix, without reactions at the interfaces between the two phases. The prepared Ag-10wt%Ti3SiC2 had a relative density of 95% and an electrical resistivity of 2.76 x 10(-3) m Omega center dot cm when compacted at 800 MPa and sintered at 950A degrees C for 1 h. The incorporation of Ti3SiC2 into Ag was found to improve its hardness without substantially compromising its electrical conductivity; this behavior was attributed to the combination of ceramic and metallic properties of the Ti3SiC2 reinforcement, suggesting its potential application in electrical contacts.
引用
收藏
页码:810 / 816
页数:7
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