PEG/SiO2-Al2O3 hybrid form-stable phase change materials with enhanced thermal conductivity

被引:142
作者
Tang, Bingtao [1 ]
Wu, Cheng [1 ]
Qiu, Meige [1 ]
Zhang, Xiwen [1 ]
Zhang, Shufen [1 ]
机构
[1] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
基金
中国国家自然科学基金;
关键词
Composite material; Sol-gel growth; Phase transition; Thermal conductivity; ACID/EXPANDED PERLITE COMPOSITE; ENERGY-STORAGE; SOLID DISPERSIONS; POLY(ETHYLENE GLYCOL); PCM; RELIABILITY; DISSOLUTION; CATALYST; SYSTEMS; FILMS;
D O I
10.1016/j.matchemphys.2013.12.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The thermal conductivity of form-stable PEG/SiO2 phase change material (PCM) was enhanced by in situ doping of Al2O3 using an ultrasound-assisted sol-gel method. Fourier transform infrared spectroscopy (FT-IR) was used to characterize the structure, and the crystal performance was characterized by the X-ray diffraction (XRD). Differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA) were used to determine the thermal properties. The phase change enthalpy of PEG/SiO2-Al2O3 reached 124J g(-1), and thermal conductivity improved by 12.8% for 3.3 wt% Al2O3 in the PCM compared with PEG/SiO2. The hybrid PCM has excellent thermal stability and form-stable effects. Crown Copyright (C) 2014 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:162 / 167
页数:6
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