Synthesis and electrochemical properties of graphene/V2O5 xerogels nanocomposites as supercapacitor electrodes

被引:54
作者
Xu, Jie [1 ]
Sun, Huajun [1 ]
Li, Zhaolong [1 ]
Lu, Shan [1 ]
Zhang, Xiaoyan [1 ]
Jiang, Shanshan [1 ]
Zhu, Quanyao [1 ]
Zakharova, Galina S. [2 ]
机构
[1] Wuhan Univ Technol, Sch Mat Sci & Engn, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
[2] Russian Acad Sci, Ural Div, Inst Solid State Chem, Ekaterinburg 620219, Russia
基金
俄罗斯基础研究基金会; 中国国家自然科学基金;
关键词
Graphene/V2O5 xerogels nanocomposites; Supercapacitor; Electrochemical property; HIGH-PERFORMANCE SUPERCAPACITORS; VANADIUM-OXIDE NANOWIRE; CARBON NANOTUBES; ENERGY-STORAGE; COMPOSITES; CAPACITORS;
D O I
10.1016/j.ssi.2013.10.060
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The graphene/V2O5 xerogels nanocomposites were synthesized by the hydrothermal method. The structure of the samples was characterized by X-ray diffraction (XRD) and high-resolution transmission electron microscopy (HRTEM). The electrochemical properties of the graphene/V2O5 xerogels nanocomposites were studied by cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge measurements as electrode materials for supercapacitor. In the graphene/V2O5 xerogels nanocomposites, graphene sheets and the layers of V2O5 xerogels (V2O5 center dot 1.6H(2)O) were stacked together. The graphene/V2O5 xerogels nanocomposites exhibited high specific capacity and high-rate capability, delivering a specific capacitance of 195.4 F/g and 184.6 F/g at the current density of 1A/g and 10 A/g between 0 and 0.65 V, respectively. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:234 / 237
页数:4
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