Photopromoted carbonylation of olefins and carbon dioxide under ambient conditions

被引：0

作者：

Yin, JM ^{[1
]}

Zhou, GY

Qi, CQ

Gao, DB

Jia, YP

Wang, XS

机构：

[1] Dalian Univ, Dept Chem & Chem Engn, Dalian 116622, Peoples R China

[2] Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116012, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2004年 / 25卷 / 07期

关键词：

carbon dioxide; photopromotion; carbonylation; ambient conditions; isotope experimental;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It was found that photopromoted carbonylation of olefins and CO2 under ambient conditions could be catalyzed by CO(OAc)(2), Co(acac)(2), CoSalen, Cobalt picolinic ester and[Co(14)-4,11-diene-N-4] I-2[5, 7, 7, 12, 14, 14-hexamethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 11-dieneatocobalt (II)]. The carbonylation of cyclohexene gave some by-products of cyclo-C6H11-CH2OH, cyclo-C6H11-CHO and cyclo-C6H11-COCH3, which were established by labelling studies with (CO2)-C-13, (CH3OH)-C-13, CD3OD and CD3COCD3. CH3(CH2)(7)-CH2OH, CH3(CH2)(7)-CHO and CH3(CH2)(7)-COCH3 were also confirmed as the by-products of carbonylation of 1-octene.

引用

页码：1285 / 1287

页数：3

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