Synthesis of polybutadiene-graft-poly(dimethylsiloxane) and polyethylene-graft-poly(dimethylsiloxane) copolymers with hydrosilylation reactions

被引：19
作者：
Ciolino, AE
Pieroni, OI
Vuano, BM
Villar, MA
Vallés, EM
机构：
[1] Univ Nacl Sur, CONICET, PLAPIQUI, RA-8000 Bahia Blanca, Buenos Aires, Argentina
[2] Univ Nacl Sur, Dept Quim, RA-8000 Bahia Blanca, Buenos Aires, Argentina
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2004年 / 42卷 / 12期
关键词：
polybutadiene; poly(dimethylsiloxane); polyethylene (PE); hydrosilylation; graft copolymers; H-1 and C-13 NMR spectroscopies; Wilkinson's catalyst; catalytic hydrogenation;
D O I：
10.1002/pola.20032
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report preliminary results for the synthesis of polyethylene-graft-poly(dimethylsiloxane) copolymers obtained by catalytic hydrogenation of polybutadiene-graft-poly(dimethylsiloxane) copolymers (PB-g-PDMS). These last copolymers were synthesized by hydrosilylation reactions between commercial polybutadiene and omega-silane poly(dimethylsiloxane). The reaction was carried in solution catalyzed by cis-dichloro bis(diethylsufide) platinum(II) salt. The PB-g-PDMS copolymers were analyzed by H-1 and C-13 NMR spectroscopies, and the relative weight percentages of the grafted poly(dimethylsiloxane) macromonomer were determined from the integrated peak areas of the spectra. (C) 2004 Wiley Periodicals, Inc.
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页码：2920 / 2930
页数：11
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