Subpicosecond kinetic polarization spectroscopic study of the complex photophysical behavior of solutions of 9,9′-bianthryl

被引：9
作者：
de Bekker, EJA [1 ]
Pugzlys, A [1 ]
Varma, CAGO [1 ]
机构：
[1] Leiden Univ, Leiden Inst Chem, Gorlaeus Labs, NL-2300 RA Leiden, Netherlands
来源：
JOURNAL OF PHYSICAL CHEMISTRY A | 2002年 / 106卷 / 25期
关键词：
D O I：
10.1021/jp012693r
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Several new aspects of the complex photophysical behavior of solutions of 9,9'-bianthryl are reported. They have been revealed by the time dependencies of the depolarization of the fluorescence and the photoinduced transient optical absorptions of these solutions, A comparison is provided with the depolarization kinetics in the case of solutions of anthracene. The observed depolarization behavior is interpreted on the basis of a theoretical treatment which is presented in some detail. The main conclusions are summarized at the end of the publication.
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页码：5974 / 5988
页数：15
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