Dynamic mechanical properties of aqueous gellan solutions in the sol-gel transition region

被引：10
|
作者：
Nakamura, K
Tanaka, Y
Sakurai, M
机构：
[1] Division of Biological Science, Faculty of Science, Hokkaido University
来源：
CARBOHYDRATE POLYMERS | 1996年 / 30卷 / 2-3期
关键词：
D O I：
10.1016/S0144-8617(96)00081-1
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Influence of the gelation of aqueous gellan solutions on the dynamic viscoelastic behavior was investigated. Dynamic shear moduli for aqueous gellan solutions (0.60-3.0wt%) were determined over the frequency range from 0.01 to 10Hz and the temperature range from 10 to 60 degrees C by the method of annular pumping between coaxial cylinders. Cole-Cole diagrams in the complex viscosity were constructed, considering temperature and frequency as variables. The complex viscosity was characterized by the circular are in the viscoelastic gel region and by the skewed circular are in the sol region. The change in the relaxation from circular are to skewed circular are caused by gelation was interpreted in terms of the change in the frequency dependency from :he Cole-Cole type to the Williams-Watts type. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：101 / 108
页数：8
相关论文
共 50 条
  • [21] Thermo-reversible sol-gel transition of aqueous solutions of patchy polymers
    Parmar, Indravadan A.
    Shedge, Aarti S.
    Badiger, Manohar V.
    Wadgaonkar, Prakash P.
    Lele, Ashish K.
    RSC ADVANCES, 2017, 7 (09): : 5101 - 5110
  • [22] Effects of SDS on the sol-gel transition of konjac glucomannan in SDS aqueous solutions
    Yin, Wanchun
    Zhang, Hongbin
    Huang, Long
    Nishinari, Katsuyoshi
    COLLOID AND POLYMER SCIENCE, 2008, 286 (6-7) : 663 - 672
  • [23] GELATION OF AQUEOUS GELATIN SOLUTIONS .2. RHEOLOGY OF THE SOL-GEL TRANSITION
    DJABOUROV, M
    LEBLOND, J
    PAPON, P
    JOURNAL DE PHYSIQUE, 1988, 49 (02): : 333 - 343
  • [24] Mechanical properties of sol-gel coatings
    Fabes, B.D., 1600, (121): : 1 - 3
  • [25] Rheology of gelatin solutions at the sol-gel transition
    Peyrelasse, J
    Lamarque, M
    Habas, JP
    ElBounia, N
    PHYSICAL REVIEW E, 1996, 53 (06): : 6126 - 6133
  • [26] Changes in structure and properties of colloid silicate solutions in sol-gel transition
    Yashchinin, I.N., 1600, Maik Nauka-Interperiodica Publishing (73):
  • [27] A percolation dynamic approach to the sol-gel transition
    Del, Gado, E.
    De Arcangelis, L.
    Coniglio, A.
    Journal of Physics A: Mathematical and General, 31 (08):
  • [28] Dynamic viscoelastic properties of silica alkoxide during the sol-gel transition
    Warlus, S
    Ponton, A
    Leslous, A
    EUROPEAN PHYSICAL JOURNAL E, 2003, 12 (02): : 275 - 282
  • [29] Dynamic viscoelastic properties of silica alkoxide during the sol-gel transition
    S. Warlus
    A. Ponton
    A. Leslous
    The European Physical Journal E, 2003, 12 : 275 - 282
  • [30] A percolation dynamic approach to the sol-gel transition
    Del Gado, E
    de Arcangelis, L
    Coniglio, A
    JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1998, 31 (08): : 1901 - 1910
12345