Absolute Configurational Assignment in Chiral Compounds through Vibrational Circular Dichroism (VCD) Spectroscopy

被引：0
作者：
Uncuta, Cornelia [1 ]
Ion, Simona [1 ]
Gherase, Dragos [1 ]
Bartha, Emeric [1 ]
Teodorescu, Florina [1 ]
Filip, Petru [1 ]
机构：
[1] Romanian Acad, CD Nenitzescu Ctr Organ Chem, Bucharest 060023, Romania
来源：
REVISTA DE CHIMIE | 2009年 / 60卷 / 01期
关键词：
VCD spectroscopy; absolute configuration; ab initio DFT calculations; FUNCTIONAL THEORY CALCULATIONS; ASYMMETRIC-SYNTHESIS; SOLUTION CONFORMATION; PREDOMINANT CONFORMATIONS; CHIROPTICAL PROPERTIES; RECEPTOR ANTAGONIST; ACID-DERIVATIVES; NATURAL-PRODUCTS; CHANNEL BLOCKER; DONOR-ACCEPTOR;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Trends and perspectives of the IR/VCD chiroptical technique in configurational and conformational assignment of chiral compounds are illustrated with significant examples from literature reports within 2003-2008 period. The advantages, as well as inherent limitations of VCD as complementary or competing technique to the classical chiroptical methods are underlined.
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页码：86 / 98
页数：13
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