Nickel phosphide nanoalloy catalyst for the selective deoxygenation of sulfoxides to sulfides under ambient H2 pressure

被引：23

作者：

Fujita, Shu ^{[1
]}

Yamaguchi, Sho ^{[1
]}

Yamazoe, Seiji ^{[2
]}

Yamasaki, Jun ^{[3
]}

Mizugaki, Tomoo ^{[1
]}

Mitsudome, Takato ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, 1-3 Machikaneyama, Toyonaka, Osaka 5608531, Japan

[2] Tokyo Metropolitan Univ, Dept Chem, 1 Minami Osawa, Hachioji, Tokyo 1920397, Japan

[3] Osaka Univ, Res Ctr Ultrahigh Voltage Electron Microscopy, 7-1 Mihogaoka, Ibaraki, Osaka 5670047, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 43期

关键词：

HIGHLY EFFICIENT DEOXYGENATION; CHEMOSELECTIVE HYDROGENATION; CONTROLLABLE SYNTHESIS; REDUCING AGENT; REDUCTION; MILD; HYDRODEOXYGENATION; MOLYBDENUM; OXIDATION; CARBON;

D O I：

10.1039/d0ob01603a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Exploring novel catalysis by less common, metal-non-metal nanoalloys is of great interest in organic synthesis. We herein report a titanium-dioxide-supported nickel phosphide nanoalloy (nano-Ni2P/TiO2) that exhibits high catalytic activity for the deoxygenation of sulfoxides. nano-Ni2P/TiO2 deoxygenated various sulfoxides to sulfides under 1 bar of H-2, representing the first non-noble metal catalyst for sulfoxide deoxygenation under ambient H-2 pressure. Spectroscopic analyses revealed that this high activity is due to cooperative catalysis by nano-Ni2P and TiO2.

引用

页码：8827 / 8833

页数：7

共 50 条

[41] Efficient photocatalytic H2 production coupling with selective oxidation of aromatic alcohol under carbon neutrality
Liu, Jiafang
Zheng, Xiuzhen
Pan, Lili
Fu, Xianliang
Zhang, Sujuan
Meng, Sugang
Chen, Shifu
APPLIED CATALYSIS B-ENVIRONMENTAL, 2021, 298
[42] Hydrogenated Molybdenum Oxide Overlayers Formed on Mo Nitride Nanosheets in Ambient-Pressure CO2/H2 Gases
Zhao, Changbao
Wang, Chao
Xin, Hui
Li, Hao
Li, Rongtan
Wang, Bin
Wei, Wei
Cui, Yi
Fu, Qiang
ACS APPLIED MATERIALS & INTERFACES, 2022, 14 (22) : 26194 - 26203
[43] Microenvironment modulation of interpenetrating-type hierarchical porous foam carbon by mild-homogeneous activation for H2 storage and CO2 capture under ambient pressure
Li, Jialin
Duan, Yufeifan
Wang, Yu
Zhang, Ye
Zhou, Jiaqi
Zhao, Wei
Yu, Junwei
Zhu, Bo
Qiao, Kun
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2024, 675 : 783 - 791
[44] Nickel supported ZIF-8.PEG modified catalyst: A designed active catalyst with high H2 productivity in steam reforming of ethanol at moderate temperature
Razavian, Marjan
Fatemi, Shohreh
Mohammadi, Meisam Malek
Nouralishahi, Amideddin
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2021, 9 (04):
[45] Poly(N-vinylpyrrolidone)-H2O2 and poly(4-vinylpyridine)-H2O2 complexes: solid H2O2 equivalents for selective oxidation of sulfides to sulfoxides and ketones to gem-dihydroperoxides
Prakash, G. K. Surya
Shakhmin, Anton
Glinton, Kevin E.
Rao, Sneha
Mathew, Thomas
Olah, George A.
GREEN CHEMISTRY, 2014, 16 (07) : 3616 - 3622
[46] Assessing the Effect of the Electron-Beam Irradiation on Pd/Ga2O3 Catalyst under Ambient Pressure
Wang, Yongzhao
Niu, Yiming
Gao, Tongtong
Liu, Siyang
Zhang, Bingsen
CHEMCATCHEM, 2020, 12 (19) : 4765 - 4769
[47] Experimental study on pyrolysis/gasification of biomass and plastics for H2 production under new dual-support catalyst
Chai, Yue
Wang, Meihong
Gao, Ningbo
Duan, Yihang
Li, Jiaqi
CHEMICAL ENGINEERING JOURNAL, 2020, 396
[48] Kinetics of selective CO oxidation in excess of H2 over the nanostructured Cu0.1Ce0.9O2-y catalyst
Sedmak, G
Hocevar, S
Levec, J
JOURNAL OF CATALYSIS, 2003, 213 (02) : 135 - 150
[49] Activated carbon supported nickel catalyst for selective CO2 hydrogenation to synthetic methane under contactless induction heating
Wang, Wei
Duong-Viet, Cuong
Truong-Phuoc, Lai
Nhut, Jean-Mario
Vidal, Loic
Pham-Huu, Cuong
CATALYSIS TODAY, 2023, 418
[50] Negative Charging of Au Nanoparticles during Methanol Synthesis from CO2/H2 on a Au/ZnO Catalyst: Insights from Operando IR and Near-Ambient-Pressure XPS and XAS Measurements
Abdel-Mageed, Ali M.
Klyushin, Alexander
Rezvani, Azita
Knop-Gericke, Axel
Schloegl, Robert
Behm, Juergen
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (30) : 10325 - 10329

← 1 2 3 4 5 →