Microwave-Assisted Azide-Alkyne Cycloaddition in Water Using a Heterogeneous Cu-Catalyst

被引：12
|
作者：
Jacob, Katharina [1 ]
Stolle, Achim [1 ]
机构：
[1] Univ Jena, Inst Tech Chem & Environm Chem ITUC, D-07743 Jena, Germany
来源：
SYNTHETIC COMMUNICATIONS | 2014年 / 44卷 / 09期
关键词：
Alkyne; copper; heterogeneous catalysis; azide; microwave; BENZYNE CLICK CHEMISTRY; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; 1,3-DIPOLAR CYCLOADDITION; REGIOSELECTIVE SYNTHESIS; COPPER NANOPARTICLES; COMPLEXES; LIQUID;
D O I：
10.1080/00397911.2013.850511
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Several triazoles have been synthesized. They were obtained by a Cu-catalyzed cycloaddition of azides and alkynes. The reaction takes place in aqueous media under microwave irradiation using a copper catalyst based on porous glass. The products have been characterized by infrared, gas chromatography-mass spectrometry, H-1 NMR, and C-13 NMR in addition to melting=point determination. Furthermore the in situ building of some azides and alkynes and the influence of the used metal species was investigated.
引用
收藏
页码：1251 / 1257
页数：7
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