12-Tungstophosphoric acid/zirconia - a highly active stable solid acid - comparison with a tungstated zirconia catalyst

被引:61
作者
Devassy, BM
Halligudi, SB [1 ]
Hegde, SG
Halgeri, AB
Lefebvre, F
机构
[1] Natl Chem Lab, Inorgan Chem & Catalysis Div, Pune 411008, Maharashtra, India
[2] Indian Petrochem Corp Ltd, Baroda 391346, Gujarat, India
[3] Lab Chem Organomet Surface, CNRS, CPE, Villeurbanne, France
关键词
D O I
10.1039/b200722c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly active and stable zirconia supported 12-tungstophosphoric acid catalyst is found to be 2-3 times more active in benzylation and acylation reactions than a tungstated zirconia catalyst.
引用
收藏
页码:1074 / 1075
页数:2
相关论文
共 9 条
[1]   Preparation of superacids by metal oxides for reactions of butanes and pentanes [J].
Arata, K .
APPLIED CATALYSIS A-GENERAL, 1996, 146 (01) :3-32
[2]   Structural and catalytic characterization of solid acids based on zirconia modified by tungsten oxide [J].
Barton, DG ;
Soled, SL ;
Meitzner, GD ;
Fuentes, GA ;
Iglesia, E .
JOURNAL OF CATALYSIS, 1999, 181 (01) :57-72
[3]   Thermal stability of 12-tungstophosphoric acid supported on zirconia [J].
López-Salinas, E ;
Hernández-Cortéz, JG ;
Schifter, I ;
Torres-García, E ;
Navarrete, J ;
Gutiérrez-Carrillo, A ;
López, T ;
Lottici, PP ;
Bersani, D .
APPLIED CATALYSIS A-GENERAL, 2000, 193 (1-2) :215-225
[4]   Unique acid catalysis of heteropoly compounds (heteropolyoxometalates) in the solid state [J].
Misono, M .
CHEMICAL COMMUNICATIONS, 2001, (13) :1141-1152
[5]   Influence of the preparative method on the activity of highly acidic WOx/ZrO2 and the relative acid activity compared with zeolites [J].
Santiesteban, JG ;
Vartuli, JC ;
Han, S ;
Bastian, RD ;
Chang, CD .
JOURNAL OF CATALYSIS, 1997, 168 (02) :431-441
[6]   n-pentane isomerization catalyzed by Fe- and Mn-containing tungstated zirconia characterized by Raman spectroscopy [J].
Scheithauer, M ;
Jentoft, RE ;
Gates, BC ;
Knözinger, H .
JOURNAL OF CATALYSIS, 2000, 191 (02) :271-274
[7]   NMR study of tungstated zirconia catalyst: characterizing the surface of tungstated zirconia and the influence of reduction treatment [J].
Shimizu, K ;
Venkatraman, TN ;
Song, WG .
APPLIED CATALYSIS A-GENERAL, 2002, 225 (1-2) :33-41
[8]  
Sreenivasan R., 1995, J CATAL, V153, P123
[9]   Sulfated zirconia and its modified versions as promising catalysts for industrial processes [J].
Yadav, GD ;
Nair, JJ .
MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 33 (1-3) :1-48